5599-30-4Relevant articles and documents
The electrochemistry of tetramesityldisilene, Mes2Si=SiMes2
Zhang, Zeng-Rong,Becker, James Y.,West, Robert C.
, p. 2719 - 2720 (2007/10/03)
The outcome of the controlled potential oxidation and reduction of a disilene, tetramesityldisilene (TMDS), indicates that the main silicon containing products involve only one silicon atom and have the general structure Mes2SiX(Y), X and Y being H, OH or F.
Rate increases in the fluorination of bulky chlorosilanes caused by ultrasound or by water
Lickiss, Paul D.,Lucas, Ronan
, p. 167 - 172 (2007/10/03)
The conversion of bulky chlorosilanes to fluorosilanes under anhydrous conditions with hexafluorosilicate salts is accelerated by ultrasound. The fluorination of sterically hindered chlorosilanes such as tBuPh2SiCl, in the absence of ultrasound, is greatly accelerated by the addition of water to the reaction mixture.