120489-36-3

Basic information

• Product Name: methyl 2-acetamido-4,6-O-benzylidene-2-deoxy-3-O-pivaloyl-α-D-glucopyranoside
• Synonyms: methyl 2-acetamido-4,6-O-benzylidene-2-deoxy-3-O-pivaloyl-α-D-glucopyranoside
• CAS NO: 120489-36-3
• Molecular Weight: 407.464
• Mol File: 120489-36-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: methyl 2-acetamido-4,6-O-benzylidene-2-deoxy-3-O-pivaloyl-α-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2-acetamido-4,6-O-benzylidene-2-deoxy-3-O-pivaloyl-α-D-glucopyranoside(120489-36-3)
• EPA Substance Registry System: methyl 2-acetamido-4,6-O-benzylidene-2-deoxy-3-O-pivaloyl-α-D-glucopyranoside(120489-36-3)

Safety Data

• Hazardous Substances Data: 120489-36-3(Hazardous Substances Data)

Upstream product

• 3282-30-2 pivaloyl chloride 
• 6619-04-1 N-((4aR,6S,7R,8R,8aS)-8-Hydroxy-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl)-acetamide 
• 88295-36-7 1-O-Methyl-2-N-acetylamino-2-deoxy-4,6-O-benzyliden-α,β-D-glucopyranosid 

Downstream Products

• 866332-85-6 2,2-Dimethyl-propionic acid (2S,3S,4R,5R,6S)-3-azido-2-benzyloxymethyl-5-tert-butoxycarbonylamino-6-methoxy-tetrahydro-pyran-4-yl ester 
• 866332-84-5 2,2-Dimethyl-propionic acid (2S,3R,4R,5S,6S)-3-acetylamino-5-azido-6-benzyloxymethyl-2-methoxy-tetrahydro-pyran-4-yl ester 
• 866332-83-4 2,2-Dimethyl-propionic acid (2S,3R,4R,5R,6R)-3-acetylamino-6-benzyloxymethyl-5-hydroxy-2-methoxy-tetrahydro-pyran-4-yl ester 

Relevant articles and documents

Orthogonally protected carbohydrate-based scaffolds

A series of orthogonally protected polyaminated carbohydrate scaffolds have been prepared on a multi-gram scale.

Selective pivaloylation of 2-acetamido-2-deoxy sugars.

Selective pivaloylation of 2-acetamido-2-deoxy-D-glucose, its methyl alpha- and beta-glycosides, and the methyl alpha-glycoside of N-acetyl-D-muramic acid under various conditions has been studied. The structures of the products were established by 1H-n.m.r. spectroscopy and acetylation. The orders of acylation, HO-6 greater than HO-3 greater than HO-1 greater than HO-4 for 2-acetamido-2-deoxy-D-glucose and HO-6 greater than HO-3 greater than HO-4 for its methyl glycosides, were established. Methyl 2-acetamido-2-deoxy-3,6-di-O-pivaloyl-alpha- and -beta-D-glucopyranosides and 2-acetamido-2-deoxy-1,3,4,6-tetra-O-pivaloyl-D-glucopyranose were hydrolysed by rabbit serum esterases.