88295-36-7

Basic information

• Product Name: 1-O-Methyl-2-N-acetylamino-2-deoxy-4,6-O-benzyliden-α,β-D-glucopyranosid
• CAS NO: 88295-36-7
• Molecular Weight: 323.346
• Mol File: 88295-36-7.mol
• Article Data: 14

Chemical Properties

• CAS DataBase Reference: 1-O-Methyl-2-N-acetylamino-2-deoxy-4,6-O-benzyliden-α,β-D-glucopyranosid(CAS DataBase Reference)
• NIST Chemistry Reference: 1-O-Methyl-2-N-acetylamino-2-deoxy-4,6-O-benzyliden-α,β-D-glucopyranosid(88295-36-7)
• EPA Substance Registry System: 1-O-Methyl-2-N-acetylamino-2-deoxy-4,6-O-benzyliden-α,β-D-glucopyranosid(88295-36-7)

Safety Data

• Hazardous Substances Data: 88295-36-7(Hazardous Substances Data)

Upstream product

• 3055-46-7 methyl N-acetyl-D-glucosamine 
• 774-48-1 (diethoxymethyl)benzene 
• 128657-58-9 methyl 2-amino-4,6-O-benzylidene-2-deoxy-α-D-glucopyranoside 
• 108-24-7 acetic anhydride 
• 7512-17-6 N-Acetyl-D-glucosamine 
• 1125-88-8 benzaldehyde dimethyl acetal 
• 6082-04-8 methyl 2-acetylamido-2-deoxy-D-glucoside 
• 100638-83-3 methyl 2-acetamido-4,6-O-benzylidene-2-deoxy-3-O--α-D-glucopyranoside 
• 67-56-1 methanol 
• 6748-94-3 methyl-[O³-acetyl-2-acetylamino-O⁴,O⁶-((R)-benzylidene)-2-deoxy-α-D-altropyranoside] 
• 66537-92-6 methyl 2,3-anhydro-4,6-benzylidene-α-D-allopyranoside 

Downstream Products

• 17327-09-2 Methyl-2-acetamido-2-deoxy-α-D-altropyranosid 
• 86988-15-0 methyl 2-acetamido-4,6-O-benzylidene-2-deoxy-3-O-trifluoromethylsulfonyl-α,β-D-glucopyranoside 
• 120489-36-3 methyl 2-acetamido-4,6-O-benzylidene-2-deoxy-3-O-pivaloyl-α-D-glucopyranoside 
• 124314-40-5 methyl 2-acetamido-4,6-O-benzylidene-2-deoxy-3-O-pivaloyl-β-D-glucopyranoside 
• 69892-44-0 methyl 2-acetylamino-3-O-benzyl-2-deoxy-α-D-glucopyranoside 
• 84048-42-0 1-O-methyl-2-amino-2-deoxy-4,6-benzylidene-α,β-D-glucopyranoside 
• 76899-76-8 1-O-Methyl-2-amino-2-deoxy-4,6-O-benzyliden-β-D-glucopyranosid 
• 100638-83-3 methyl 2-acetamido-4,6-O-benzylidene-2-deoxy-3-O--α-D-glucopyranoside 
• 260970-14-7 methyl 2,3-di-O-benzoyl-4,6-dideoxy-α-L-lyxo-hexopyranosyl-(1->3)-2-acetamido-4,6-O-benzylidene-2-deoxy-α-D-glucopyranoside 
• 260970-15-8 methyl 2-O-benzoyl-3-O-benzyl-4-deoxy-4-fluoro-α-L-rhamnopyranosyl-(1->3)-2-acetamido-4,6-O-benzylidene-2-deoxy-α-D-glucopyranoside 
• 354986-48-4 methyl 2-acetamido-4,6-O-benzylidene-2-deoxy-3-O-(2-picolinyl)-α-D-glucopyranoside 
• 144789-65-1 methyl 2-acetamido-3-O-benzyl-4,6-O-benzylidene-2-deoxy-α-D-glucopyranoside 
• 354986-45-1 methyl N-acetyl-N-benzyl-2-amino-2-deoxy-3-O-benzyl-4,6-O-benzylidene-α-D-glucopyranoside 
• 651736-01-5 methyl 2-amino-4,6-O-benzylidene-2-deoxy-α-D-allopyranoside 

Relevant articles and documents

Ultrasonication-Assisted Synthesis of a d-Glucosamine-Based β-CD Inclusion Complex and Its Application as an Aqueous Heterogeneous Organocatalytic System

For the first time, an inclusion complex has been crafted between a carbohydrate-based molecule and a β-cyclodextrin (CD) hydrophobic cavity for asymmetric catalytic applications. This novel d-glucosamine-based inclusion compound has been synthesized in h

Diaminohexopyranosides as ligands in half-sandwich ruthenium(II), rhodium(III), and iridium(III) complexes

The syntheses of methyl 2,3-diamino-4,6-O-benzylidene-2,3-dideoxy-α-d-hexopyranosides of glucose, mannose, gulose, and talose and methyl 2-amino-4,6-benzylidene-2,3-dideoxy-3-tosylamido-α-d-glucopyranoside are exhaustively presented, as well as their application as ligands in half-sandwich ruthenium(II), rhodium(III), and iridium(III) complexes. The complex formation occurs highly diastereoselectively, creating a stereogenic metal center. The molecular structures of the ligands and their complexes were investigated by X-ray structure analysis, NMR spectroscopy, polarimetry, and DFT methods. The diamino monosaccharide complexes have been subjected to antitumor activity studies. In vitro tests of a few ruthenium complexes against different cancer cell types showed antiproliferative activities 4-10 times lower than that of cisplatin.

2,4,6-Trichloro-1,3,5-triazine (TCT) mediated one-pot sequential functionalisation of glycosides for the generation of orthogonally protected monosaccharide building blocks

Orthogonally protected monosaccharide building blocks have been prepared using TCT in a one-pot multicomponent transformation. The process involves successive steps of arylidene acetalation, esterification and regioselective reductive acetal cleavage. High regioselectivity, scope for using a broad range of substrates, functional group tolerance, mild reaction conditions, easy handling process and wide application range are a few advantages of the current process.