120506-39-0

Basic information

• Product Name: Silane, [4-(bromomethyl)phenoxy](1,1-dimethylethyl)dimethyl-
• CAS NO: 120506-39-0
• Molecular Formula: C13H21BrOSi
• Molecular Weight: 301.299
• Mol File: 120506-39-0.mol
• Article Data: 21

Chemical Properties

• CAS DataBase Reference: Silane, [4-(bromomethyl)phenoxy](1,1-dimethylethyl)dimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, [4-(bromomethyl)phenoxy](1,1-dimethylethyl)dimethyl-(120506-39-0)
• EPA Substance Registry System: Silane, [4-(bromomethyl)phenoxy](1,1-dimethylethyl)dimethyl-(120506-39-0)

Safety Data

• Hazardous Substances Data: 120506-39-0(Hazardous Substances Data)

Upstream product

• 623-05-2 (4-hydroxyphenyl)methanol 
• 106-44-5 p-cresol 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 133642-20-3 4-(tert-butyldimethylsilanyloxy)benzoic acid methyl ester 
• 351-70-2 benzyl trifluoroacetate 
• 156878-45-4 4-<(tert-Butyldimethylsilyl)oxy>benzyl trifluoroacetate 
• 123-08-0 4-hydroxy-benzaldehyde 
• 120743-99-9 p-[(tert-butyldimethylsilyl)oxy]benzaldehyde 
• 62790-85-6 tert-Butyl(dimethyl)-(4-methylphenoxy)silane 
• 138585-08-7 (4-((tert-butyldimethylsilyl)oxy)phenyl)methanol 

Downstream Products

• 872254-19-8 (S)-1-(4-Hydroxybenzyl)-5-(2-phenoxymethyl-pyrrolidine-1-sulfonyl)-1H-indole-2,3-dione 
• 134029-60-0 (Z)-4-<2-(3',4',5'-Trimethoxyphenyl)ethenyl>phenol 
• 134029-58-6 (Z)-1-<4-<(tert-butyldimethylsilyl)oxy>phenyl>-2-(3,4,5-trimethoxyphenyl)ethene 
• 134029-67-7 (E)-1-<4-<(tert-butyldimethylsilyl)oxy>phenyl>-2-(3,4,5-trimethoxyphenyl)ethene 
• 156878-50-1 2-Amino-4-[2-(3,4,5-trimethoxy-phenyl)-ethyl]-phenol 
• 156878-47-6 2-Amino-4-<(Z)-2-(3',4',5'-trimethoxyphenyl)ethenyl>phenol 
• 1391092-01-5 (4-(azidomethyl)phenoxy)(tert-butyl)dimethylsilane 
• 245076-30-6 3-oxo-17α-pregna-4-ene-7α-[4-(t-butyldimethylsilyloxy)-benzylthia]-21,17-carbolactone 

Relevant articles and documents

Reinvestigation of the synthesis of “covalent-assembly” type probes for fluoride ion detection. Identification of novel 7-(diethylamino)coumarins with aggregation-induced emission properties

An unprecedented C-3 functionalization of 4-(diethylamino)salicylaldehyde through a Friedel-Crafts type alkylation reaction has been discovered during the synthesis of “covalent-assembly”-based fluorescent probes for detection of fluoride ions. The resulting Friedel-Crafts adduct was successfully used for the preparation of two novel 8-substituted 7-(diethylamino)coumarin dyes. The photophysical study of these fluorophores has enabled us to highlight their remarkable aggregation-induced emission (AIE) properties characterized by a yellow-orange emission of aggregates in water. Therefore, 4-(tert-butyldimethylsilyloxy)benzyl substituent was identified as a novel AIE-active moiety which could be seen as a possible alternative to popular tetraphenylethylene (TPE).

Novel methinic functionalized and dendritic C-scorpionates

The study of chelating ligands is undoubtedly one of the most significant fields of research in chemistry. The present work is directed to the synthesis of new functionalized derivatives of tripodal C-scorpionate compounds. Tris-2,2,2-(1-pyrazolyl)ethanol, HOCH2C(pz)3 (1), one of the most important derivatives of hydrotris(pyrazolyl)methane, was used as a building block for the synthesis of new functionalized C-scorpionates, aiming to expand the scope of this unexplored class of compounds. The first dendritic C-scorpionate was successfully prepared and used in the important industrial catalytic reactions, Sonogashira and Heck C-C cross-couplings.

Synthesis of N-benzyl substituted 1,4-imino-L-lyxitols with a basic functional group as selective inhibitors of Golgi α-mannosidase IIb

Inhibition of the biosynthesis of complex N-glycans in the Golgi apparatus is one of alternative ways to suppress growth of tumor tissue. Eight N-benzyl substituted 1,4-imino-L-lyxitols with basic functional groups (amine, amidine, guanidine), hydroxyl an