1391092-01-5

Basic information

• Product Name: (4-(azidomethyl)phenoxy)(tert-butyl)dimethylsilane
• Synonyms: (4-(azidomethyl)phenoxy)(tert-butyl)dimethylsilane
• CAS NO: 1391092-01-5
• Molecular Weight: 263.415
• Mol File: 1391092-01-5.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (4-(azidomethyl)phenoxy)(tert-butyl)dimethylsilane(CAS DataBase Reference)
• NIST Chemistry Reference: (4-(azidomethyl)phenoxy)(tert-butyl)dimethylsilane(1391092-01-5)
• EPA Substance Registry System: (4-(azidomethyl)phenoxy)(tert-butyl)dimethylsilane(1391092-01-5)

Safety Data

• Hazardous Substances Data: 1391092-01-5(Hazardous Substances Data)

Upstream product

• 120743-99-9 p-[(tert-butyldimethylsilyl)oxy]benzaldehyde 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 123-08-0 4-hydroxy-benzaldehyde 
• 623-05-2 (4-hydroxyphenyl)methanol 
• 55116-31-9 1-(azidomethyl)-4-hydroxybenzene 
• 138585-08-7 (4-((tert-butyldimethylsilyl)oxy)phenyl)methanol 
• 120506-39-0 (4-(bromomethyl)phenoxy) (tert-butyl) dimethylsilane 
• 133642-20-3 4-(tert-butyldimethylsilanyloxy)benzoic acid methyl ester 

Downstream Products

• 117635-43-5 tert-butyl(4-(1-isocyanovinyl)phenoxy)dimethylsilane 
• 1391092-13-9 4-ferrocenyl-1-((4-tert-butyldimethylsilyloxy)benzyl)-1H-1,2,3-triazole 

Relevant articles and documents

Cyclic Diaryl λ3-Bromanes: A Rapid Access to Molecular Complexity via Cycloaddition Reactions

Biaryls have widespread applications in organic synthesis. However, sequentially polysubstituted biaryls are underdeveloped due to their challenging preparation. Herein, we report the synthesis of dissymetric 2,3,2′,3′,4-substituted biaryls via pericyclic reactions of cyclic diaryl λ3-bromanes. The functional groups tolerance and atom economy allow access to molecular complexity in a single reaction step. Continuous flow protocol has been designed for the scale-up of the reaction, while postfunctionalizations have been developed taking advantage of the residual Br-atom.

Redox reaction between benzyl azides and aryl azides: concerted synthesis of aryl nitriles and anilines

A unique and novel reaction between benzyl azides and aryl azides is described to synthesize aryl nitriles and anilines concurrently, which is catalyzed with a photoactivated diruthenium complex. N-Unsubstituted imines (N-H imines) are generated first from benzyl azides, followed by the hydrogen transfer reaction between N-H imines and aryl azides. A wide range of aryl nitriles and anilines were synthesized under neutral and mild reaction conditions.