1206692-24-1

Basic information

• Product Name: (NC₅H₄C(S)NC₆H₄OCH₃)AuCl₂
• CAS NO: 1206692-24-1
• Molecular Weight: 511.182
• Mol File: 1206692-24-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (NC₅H₄C(S)NC₆H₄OCH₃)AuCl₂(CAS DataBase Reference)
• NIST Chemistry Reference: (NC₅H₄C(S)NC₆H₄OCH₃)AuCl₂(1206692-24-1)
• EPA Substance Registry System: (NC₅H₄C(S)NC₆H₄OCH₃)AuCl₂(1206692-24-1)

Safety Data

• Hazardous Substances Data: 1206692-24-1(Hazardous Substances Data)

Upstream product

• 13225-85-9 N-(4-methoxy-phenyl)-α-thiopicolinamide 

Relevant articles and documents

The cycloauration of pyridine-2-thiocarboxamide ligands

Reactions of H[AuCl4] with N-substituted 2-pyridine thiocarboxamide ligands 2-(C5H4N)C(S)NHR (R = p-C6H4Me, CH2Ph, Me, p-C6H4OMe) gave cycloaurated derivatives {(C5H4N)C(S)NR}AuCl2, with the ligand bonded as the thiol tautomer through the deprotonated SH group and the pyridine N atom to give a five-membered metallacyclic ring. The X-ray structure determination of the R = CH2Ph derivative shows a square-planar gold(III) complex that dimerises in the solid state by weak Au···S intermolecular interactions. In contrast, in the reaction of H[AuCl4] with 2-(C5H4N)C(S)NHR where R = 2-pyridyl, the ligand was oxidised to give a 1,2,4-thiadiazolo[2,3-a]pyridinium heterocyclic ring that was crystallographically characterised.