121197-51-1

Basic information

• Product Name: (E)-N-(4-fluorobenzylidene)-P,P-diphenylphosphinic amide
• Synonyms: (E)-N-(4-fluorobenzylidene)-P,P-diphenylphosphinic amide
• CAS NO: 121197-51-1
• Molecular Weight: 323.306
• Mol File: 121197-51-1.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (E)-N-(4-fluorobenzylidene)-P,P-diphenylphosphinic amide(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-N-(4-fluorobenzylidene)-P,P-diphenylphosphinic amide(121197-51-1)
• EPA Substance Registry System: (E)-N-(4-fluorobenzylidene)-P,P-diphenylphosphinic amide(121197-51-1)

Safety Data

• Hazardous Substances Data: 121197-51-1(Hazardous Substances Data)

Upstream product

• 459-23-4 4-fluorobenzaldoxime 
• 1079-66-9 chloro-diphenylphosphine 
• 459-57-4 4-fluorobenzaldehyde 
• 5994-87-6 diphenylphosphinamide 
• 459-23-4 (E)-4-fluorobenzaldehyde oxime 

Downstream Products

• 1242635-70-6 methyl (R)-2-((N-(diphenylphosphoryl)amino)(4-fluorophenyl)methyl)acrylate 
• 1023287-85-5 ethyl (2S)-1-(diphenylphosphoryl)-2-(4-fluorophenyl)-2,5-dihydro-1H-pyrrole-3-carboxylate 
• 121197-59-9 2-(diphenylphosphinoyl)-3-(4-fluorophenyl)oxaziridine 

Relevant articles and documents

(Thiolan-2-yl)diphenylmethyl benzyl ether/N,N′-diarylurea cocatalyzed asymmetric aziridination of cinnamyl bromide and aryl aldimine

A dual catalyst system using THT-based chiral sulfide 2a and H-bond donor 10a was developed for the asymmetric imino Corey-Chaykovsky reaction. Under the optimum reaction conditions, cinnamyl bromide reacted with a wide scope of N-diphenylphosphinic aldim

Stereoselective synthesis of α-silylamines by the direct addition of silyl anions to activated imines

(Chemical Equation Presented) A highly efficient stereoselective synthesis of unusual α-silylamines via a direct silyl anion addition reaction is reported. This approach is convergent and avoids any problematic aza-Brook shifts of the anionic intermediate