459-57-4Relevant articles and documents
A porphyrin-conjugated TiO2/CoFe2O4nanostructure photocatalyst for the selective production of aldehydes under visible light
Ghobadifard, Mahdieh,Safaei, Elham,Radovanovic, Pavle V.,Mohebbi, Sajjad
, p. 8032 - 8044 (2021)
We investigated the photocatalytic performance of a magnetic nanohybrid of CoFe2O4 and TiO2 hetero-nanostructures (TiO2/CoFe2O4) conjugated with zinc tetrakis carboxyphenyl porphyrin (ZnTCPP) for controlled oxidation of alcohols to aldehydes under visible
Synthesis, characterization, crystal structure, and catalytic activity of an end-on azido-bridged polymeric copper(Ii) complex derived from 4-methyl-2- [(3-methylaminopropylimino)methyl]phenol
Liu, Li-Jun
, p. 956 - 960 (2017)
An end-on azido-bridged polymeric copper(II) complex, [CuL(μ1,1-N3)]n (HL D 4-methyl-2- [(3-methylaminopropylimino)methyl]phenol), was synthesized and characterized by elemental analysis, IR spectra, and single-crystal X-r
Cobalt(II) supported on ethylenediamine-functionalized nanocellulose as an efficient catalyst for room temperature aerobic oxidation of alcohols
Shaabani, Ahmad,Keshipour, Sajjad,Hamidzad, Mona,Seyyedhamzeh, Mozhdeh
, p. 111 - 115 (2014)
Ethylenediamine-functionalized nanocellulose complexed with cobalt(II) was found to be a highly efficient heterogeneous catalyst for the room temperature aerobic oxidation of various types of primary and secondary benzylic alcohols into their correspondin
Controlled reduction of activated primary and secondary amides into aldehydes with diisobutylaluminum hydride
Azeez, Sadaf,Kandasamy, Jeyakumar,Sabiah, Shahulhameed,Sureshbabu, Popuri
supporting information, p. 2048 - 2053 (2022/03/31)
A practical method is disclosed for the reduction of activated primary and secondary amides into aldehydes using diisobutylaluminum hydride (DIBAL-H) in toluene. A wide range of aryl and alkyl N-Boc, N,N-diBoc and N-tosyl amides were converted into the corresponding aldehydes in good to excellent yields. Reduction susceptible functional groups such as nitro, cyano, alkene and alkyne groups were found to be stable. Broad substrate scope, functional group compatibility and quick conversions are the salient features of this methodology.
METHOD FOR OXIDATIVE CLEAVAGE OF COMPOUNDS WITH UNSATURATED DOUBLE BOND
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Paragraph 0053-0054; 0062-0063, (2021/03/19)
A method for oxidative cleavage of a compound with an unsaturated double bond is provided. The method comprises the following step: (A) providing a compound (I) with an unsaturated double bond, a reagent with trifluoromethyl, and a catalyst; wherein the catalyst is represented by the following formula (II): M(O)mL1yL2z (II); wherein, M, L1, L2, m, y, z, R1, R2 and R3 are defined in the specification; and (B) mixing the compound with an unsaturated double bond and the reagent with a trifluoromethyl to perform an oxidation of the compound with the unsaturated double bond by using the catalyst at air or an oxygen condition to get a compound presented as formula (III):