175235-76-4

Basic information

• Product Name: Benzene, 1-[bis(phenylthio)methyl]-4-fluoro-
• CAS NO: 175235-76-4
• Molecular Formula: C19H15FS2
• Molecular Weight: 326.459
• Mol File: 175235-76-4.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Benzene, 1-[bis(phenylthio)methyl]-4-fluoro-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-[bis(phenylthio)methyl]-4-fluoro-(175235-76-4)
• EPA Substance Registry System: Benzene, 1-[bis(phenylthio)methyl]-4-fluoro-(175235-76-4)

Safety Data

• Hazardous Substances Data: 175235-76-4(Hazardous Substances Data)

Upstream product

• 459-57-4 4-fluorobenzaldehyde 
• 108-98-5 thiophenol 
• 882-33-7 diphenyldisulfane 
• 1427026-26-3 1-(4-methylbenzenesulfonyl)-4-(4-fluorobenzene)-1H-1,2,3-triazole 
• 210422-66-5 4-fluorobenzaldehyde p-toluenesulfonylhydrazone 
• 459-56-3 4-fluorobenzylic alcohol 
• 100-53-8 phenylmethanethiol 

Downstream Products

• 1229-75-0 (2-(4-fluorophenyl)ethene-1,1-diyl)dibenzene 

Relevant articles and documents

Dithioacetalization or thioetherification of benzyl alcohols using 9-mesityl-10-methylacridinium perchlorate photocatalyst

We report herein the use of 9-mesityl-10-methylacridinium perchlorate as the visible-light photocatalyst for dithioacetalization or thioetherification of benzyl alcohols in one pot using aerial dioxygen as a terminal oxidant. EPR analysis and Stern-Volmer

A Transition-Metal-Free and Base-Mediated Carbene Insertion into Sulfur-Sulfur and Selenium-Selenium Bonds: An Easy Access to Thio- and Selenoacetals

A transition-metal-free and base-mediated carbene insertion across sulfur-sulfur and selenium-selenium bonds has been developed by employing N-tosylhydrazone as a stable and safe carbene precursor. The ylide formation from carbene followed by Stevens rearrangement are considered to be the key steps. This thiol and selenol-free protocol delivers thioacetals and selenoacetals in good to excellent yields in short reaction time with good functional group tolerance. A one-pot synthesis involving in situ generation of tosylhydrazone has also been demonstrated. (Figure presented.).

Rhodium-catalyzed denitrogenative thioacetalization of N-sulfonyl-1,2,3-triazoles with disulfides: An entry to diverse transformation of terminal alkynes

An efficient and useful rhodium-catalyzed denitrogenative thioacetalization of N-sulfonyl-1,2,3-triazoles has been developed for the first time. The protocol uses readily available N-sulfonyl-1,2,3-triazoles and diaryl disulfides as the starting materials. The corresponding hydrolytic and reductive products with thioacetals were obtained in good to excellent yields, and the reactions were carried out easily under mild conditions with tolerance of some functional groups. Furthermore, the generated thioacetals could be transformed into some useful compounds. Therefore, the present method provides a novel and valuable strategy for the diverse transformation of alkynes.