175235-76-4

Basic information

• Product Name: Benzene, 1-[bis(phenylthio)methyl]-4-fluoro-
• CAS NO: 175235-76-4
• Molecular Formula: C19H15FS2
• Molecular Weight: 326.459
• Mol File: 175235-76-4.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Benzene, 1-[bis(phenylthio)methyl]-4-fluoro-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-[bis(phenylthio)methyl]-4-fluoro-(175235-76-4)
• EPA Substance Registry System: Benzene, 1-[bis(phenylthio)methyl]-4-fluoro-(175235-76-4)

Safety Data

• Hazardous Substances Data: 175235-76-4(Hazardous Substances Data)

Upstream product

• 100-53-8 phenylmethanethiol 
• 459-56-3 4-fluorobenzylic alcohol 
• 108-98-5 thiophenol 
• 210422-66-5 4-fluorobenzaldehyde p-toluenesulfonylhydrazone 
• 882-33-7 diphenyldisulfane 
• 1427026-26-3 1-(4-methylbenzenesulfonyl)-4-(4-fluorobenzene)-1H-1,2,3-triazole 
• 459-57-4 4-fluorobenzaldehyde 

Downstream Products

• 1229-75-0 (2-(4-fluorophenyl)ethene-1,1-diyl)dibenzene 

Relevant articles and documents

Dithioacetalization or thioetherification of benzyl alcohols using 9-mesityl-10-methylacridinium perchlorate photocatalyst

We report herein the use of 9-mesityl-10-methylacridinium perchlorate as the visible-light photocatalyst for dithioacetalization or thioetherification of benzyl alcohols in one pot using aerial dioxygen as a terminal oxidant. EPR analysis and Stern-Volmer

A Transition-Metal-Free and Base-Mediated Carbene Insertion into Sulfur-Sulfur and Selenium-Selenium Bonds: An Easy Access to Thio- and Selenoacetals

A transition-metal-free and base-mediated carbene insertion across sulfur-sulfur and selenium-selenium bonds has been developed by employing N-tosylhydrazone as a stable and safe carbene precursor. The ylide formation from carbene followed by Stevens rearrangement are considered to be the key steps. This thiol and selenol-free protocol delivers thioacetals and selenoacetals in good to excellent yields in short reaction time with good functional group tolerance. A one-pot synthesis involving in situ generation of tosylhydrazone has also been demonstrated. (Figure presented.).

Reduction of titanocene dichloride with dysprosium: Access to a stable titanocene(II) equivalent for phosphite-free Takeda carbonyl olefination

The reduction of titanocene dichloride with dysprosium yields a new titanocene(ii) equivalent without the need for further stabilising ligands. This reagent can be employed in combination with dithioacetals for the olefination of different carbonyl groups and allows for a simplified all-in-one procedure.