14629-55-1

Basic information

• Product Name: p-Fluorobenzyloxytrimethylsilane
• Synonyms: p-Fluorobenzyloxytrimethylsilane
• CAS NO: 14629-55-1
• Molecular Formula: C₁₀H₁₅FOSi
• Molecular Weight: 198.31
• Mol File: 14629-55-1.mol
• Article Data: 15

Chemical Properties

• Appearance: /
• CAS DataBase Reference: p-Fluorobenzyloxytrimethylsilane(CAS DataBase Reference)
• NIST Chemistry Reference: p-Fluorobenzyloxytrimethylsilane(14629-55-1)
• EPA Substance Registry System: p-Fluorobenzyloxytrimethylsilane(14629-55-1)

Safety Data

• Hazardous Substances Data: 14629-55-1(Hazardous Substances Data)

Upstream product

• 459-56-3 4-fluorobenzylic alcohol 
• 999-97-3 1,1,1,3,3,3-hexamethyl-disilazane 
• 993-07-7 trimethylsilan 
• 201230-82-2 carbon monoxide 
• 459-57-4 4-fluorobenzaldehyde 
• 4039-32-1 lithium hexamethyldisilazane 

Downstream Products

• 459-57-4 4-fluorobenzaldehyde 
• 459-56-3 4-fluorobenzylic alcohol 
• 459-23-4 4-fluorobenzaldoxime 
• 18539-44-1 (±)-2-[(4-fluorobenzyl)oxy]tetrahydropyran 
• 456-19-9 4-fluorobenzal chloride 

Relevant articles and documents

Magnetic nanoparticle-supported DABCO tribromide: A versatile nanocatalyst for the synthesis of quinazolinones and benzimidazoles and protection/deprotection of hydroxyl groups

1,4-Diazabicyclo[2.2.2]octane tribromide supported on magnetic Fe3O4 nanoparticles (MNPs-DABCO tribromide) as a novel heterogeneous tribromide type compound was found to be an efficient and reusable nanocatalyst for the one-pot synthesis of 2-arylquinazolin-4(3H)-ones and 2-aryl-1H-benzo[d]imidazoles through oxidative cyclization of aldehydes with 2-aminobenzamides and 1,2-phenylenediamine, respectively. Also, MNPs-DABCO tribromide catalyzed trimethylsilylation/tetrahydropyranylation and desilylation/depyranylation of a wide variety of alcohols and phenols through changing the solvent medium at room temperature.

{[[K.18-Crown-6]Br3}n: A tribromide catalyst for the catalytic protection of amines and alcohols

{[K.18-Crown-6]Br3}n, a unique tribromide-type catalyst, was utilized for the N-boc protection of amines and trimethylsilylation (TMS) and tetrahydropyranylation (THP) of alcohols. The method is general for the preparation of N-boc derivatives of aliphatic (acyclic and cyclic) and aromatic, and primary and secondary amines and also various TMS-ethers and THP-ethers. The simple separation of the catalyst from the product is one of the many advantages of this method.

[H2-Cryptand 222]2+(Br3-) 2 as a tribromide-type catalyst for the trimethylsilylation/ tetrahydropyranylation of alcohols

A stable organic tribromide, [H2-cryptand 222] 2+(Br3-)2 was utilized as an active catalyst for the trimethylsilylation/ tetrahydropyranylation of alcohols. The method is general for the preparation of OH-protected aliphatic (acyclic and cyclic), aromatic, primary, secondary and tertiary alcohols.