32691-93-3

Basic information

• Product Name: α,α-dimethoxy-4-fluorotoluene
• Synonyms: α,α-dimethoxy-4-fluorotoluene
• CAS NO: 32691-93-3
• Molecular Weight: 170.184
• Mol File: 32691-93-3.mol
• Article Data: 17

Chemical Properties

• CAS DataBase Reference: α,α-dimethoxy-4-fluorotoluene(CAS DataBase Reference)
• NIST Chemistry Reference: α,α-dimethoxy-4-fluorotoluene(32691-93-3)
• EPA Substance Registry System: α,α-dimethoxy-4-fluorotoluene(32691-93-3)

Safety Data

• Hazardous Substances Data: 32691-93-3(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 459-57-4 4-fluorobenzaldehyde 
• 405-99-2 para-fluorostyrene 
• 149-73-5 trimethyl orthoformate 

Downstream Products

• 71037-43-9 (4-Fluoro-phenyl)-methoxy-methyl-hydroperoxide 
• 71037-45-1 C₁₆H₁₆F₂O₄ 
• 56377-73-2 α-Chlor-p-fluorbenzyl-methyl-ether 
• 114533-84-5 1-Fluoro-4-(1,3,3-trimethoxy-propyl)-benzene 
• 613672-67-6 allyl 2-acetamido-4,6-O-(4-fluorobenzylidene)-2-deoxy-α-D-glucopyranoside 
• 515134-86-8 allyl 4,6-O-(4-fluorobenzylidene)-α-D-glucopyranoside 
• 459-57-4 4-fluorobenzaldehyde 

Relevant articles and documents

Thiol-initiated photocatalytic oxidative cleavage of the C=C bond in olefins and its extension to direct production of acetals from olefins

The oxidative cleavage of olefins to produce aldehydes/ketones is an important reaction in organic syntheses. In this manuscript, a mild and operationally simple protocol for the aerobic oxidation of olefins to produce carbonyl compounds was realized over ZnIn2S4under visible light, using air as the oxidant and a thiol as the initiator. It was proposed that the photogenerated holes over ZnIn2S4attack the thiol to produce thiyl radicals, which initiate the oxidative cleavage of the C=C bond in olefins to produce aldehydes/ketones. By further coupling with the condensation between the as-obtained aldehydes/ketones and alcohols, this strategy can also be applied to the production of different acetals directly from the olefins. This study demonstrates a new pathway to realize the oxidative cleavage of olefins to produce aldehydes/ketones, and also provides a new protocol for the production of acetals directly from the olefins.

A Mechanistic Probe into 1,2-cis Glycoside Formation Catalyzed by Phenanthroline and Further Expansion of Scope

Phenanthroline, a rigid and planar compound with two fused pyridine rings, has been used as a powerful ligand for metals and a binding agent for DNA/RNA. We discovered that phenanthroline could be used as a nucleophilic catalyst to efficiently access high

Amino acid derivative, feed composition and application thereof

The invention provides an amino acid derivative, a feed composition and application thereof, and belongs to the technical field of animal feed additives. The amino acid derivative is a compound with astructure shown as a formula (I), and a stereoisomer, a tautomer, a solvate, a metabolite, a feed acceptable salt or a prodrug thereof. In formula (I) shown in the specification, Z is a C1-C3 alkylene group. X is an indole ring group with a structure shown as a formula (II). The formula (II) is shown in the specification, wherein Y is phenyl with the structure shown in the formula (III) shown inthe specification. The amino acid derivative is used as an animal feed additive, and can promote the growth of animals and improve the feed conversion.