121440-71-9

Basic information

• Product Name: Carbonic acid, (2E)-1,3-diphenyl-2-propenyl ethyl ester
• CAS NO: 121440-71-9
• Molecular Formula: C18H18O3
• Molecular Weight: 282.339
• Mol File: 121440-71-9.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Carbonic acid, (2E)-1,3-diphenyl-2-propenyl ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Carbonic acid, (2E)-1,3-diphenyl-2-propenyl ethyl ester(121440-71-9)
• EPA Substance Registry System: Carbonic acid, (2E)-1,3-diphenyl-2-propenyl ethyl ester(121440-71-9)

Safety Data

• Hazardous Substances Data: 121440-71-9(Hazardous Substances Data)

Upstream product

• 62668-02-4 (E)-1,3-diphenyl-2-propen-1-ol 
• 541-41-3 chloroformic acid ethyl ester 
• 14371-10-9 (E)-3-phenylpropenal 
• 4663-33-6 1,3-diphenyl-3-hydroxypropene 

Downstream Products

• 121440-87-7 (+)-(S,E)-N-benzyl-(1,3-diphenyl-2-propenyl)amine 
• 95071-02-6 dimethyl 2-[(E)-(S)-1,3-diphenylallyl]-malonate 
• 95071-02-6 (R)-methyl 2-carbomethoxy-3,5-diphenylpent-4-enoate 
• 177468-91-6 (E)-dimethyl (1,3-diphenylprop-2-en-1-yl)propanedioate 
• 121440-87-7 (-)-(R,E)-N-benzyl-(1,3-diphenyl-2-propenyl)amine 
• 121440-76-4 (3,4-Dimethoxy-benzyl)-((E)-(R)-1,3-diphenyl-allyl)-amine 
• 121440-78-6 (E)-N-(1,3-diphenyl-1λ³-allyl)-4-methylbenzenesulfonamide 
• 1346158-67-5 (E)-1-(1,3-diphenylallyl)-1H-benzo[d][1,2,3]triazole 
• 132014-29-0 (S)-(E)-1,3-diphenylprop-2-en-1-ol 
• 1062573-84-5 (1R)-(1,3-diphenylallyl)-(4-methoxyphenyl)amine 
• 1062573-86-7 (4-chloro-phenyl)-(1,3-diphenylallyl)amine 
• 1062573-88-9 1-(1,3-diphenylallyl)-2,3-dihydro-1H-indole 

Relevant articles and documents

Steric effects in enantioselective allylic alkylation catalysed by cationic (η3-allyl)palladium complexes bearing chiral pyridine-aziridine ligands

Enantiopure N,N′-bidentate ligands (N,N′)*, containing substituted aziridine and aza-aromatic rings, were prepared from imines derived from (S)-valinol or (R)-phenylglycinol and heteroaromatic aldehydes (2-pyridine-, 6-benzyl-2-pyridine-, 2- and 8-quinoli

Palladium/BINAP(S)-catalyzed asymmetric allylic amination

(Chemical Equation Presented) The enantioselective allylic amination of acyclic allylic carbonates catalyzed by a palladium/(S)-BINAP(S) system was investigated. Amination of several substrates proceeded with high ee. Crotyl carbonates show an unusually high regioselectivity for the branched isomer. The use of (S)-TolBINAP(S) and (S)-3,5-xylyl-BINAP(S) as ligands was found to increase the enantioselectivity of the aminations. A P,S binding mode of the BINAP(S) ligand was found in an X-ray crystallographic study.