121468-87-9

Basic information

• Product Name: (2Z,4E)-5-[(S)-4-(tert-Butyl-dimethyl-silanyloxy)-2,6,6-trimethyl-cyclohex-1-enyl]-3-methyl-penta-2,4-dienal
• Synonyms: (2Z,4E)-5-[(S)-4-(tert-Butyl-dimethyl-silanyloxy)-2,6,6-trimethyl-cyclohex-1-enyl]-3-methyl-penta-2,4-dienal
• CAS NO: 121468-87-9
• Molecular Weight: 348.601
• Mol File: 121468-87-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2Z,4E)-5-[(S)-4-(tert-Butyl-dimethyl-silanyloxy)-2,6,6-trimethyl-cyclohex-1-enyl]-3-methyl-penta-2,4-dienal(CAS DataBase Reference)
• NIST Chemistry Reference: (2Z,4E)-5-[(S)-4-(tert-Butyl-dimethyl-silanyloxy)-2,6,6-trimethyl-cyclohex-1-enyl]-3-methyl-penta-2,4-dienal(121468-87-9)
• EPA Substance Registry System: (2Z,4E)-5-[(S)-4-(tert-Butyl-dimethyl-silanyloxy)-2,6,6-trimethyl-cyclohex-1-enyl]-3-methyl-penta-2,4-dienal(121468-87-9)

Safety Data

• Hazardous Substances Data: 121468-87-9(Hazardous Substances Data)

Upstream product

• 73198-78-4 α-(Trimethylsilyl)-tert-butylacetaldimine 
• 121468-86-8 (E)-4-[(S)-4-(tert-Butyl-dimethyl-silanyloxy)-2,6,6-trimethyl-cyclohex-1-enyl]-but-3-en-2-one 
• 121401-81-8 (S)-4-(1-Methoxy-1-methyl-ethoxymethyl)-3,5,5-trimethyl-cyclohex-3-enol 
• 76686-22-1 (S)-4-Hydroxy-2,6,6-trimethyl-cyclohex-1-enecarbaldehyde 
• 76686-21-0 (3S)-3-Hydroxy-β-cyclogeraniol 
• 121401-86-3 (E)-4-[(S)-4-(tert-Butyl-dimethyl-silanyloxy)-2,6,6-trimethyl-cyclohex-1-enyl]-but-3-en-2-ol 
• 121401-85-2 (E)-3-[(S)-4-(tert-Butyl-dimethyl-silanyloxy)-2,6,6-trimethyl-cyclohex-1-enyl]-acrylonitrile 
• 121429-38-7 (E)-3-[(S)-4-(tert-Butyl-dimethyl-silanyloxy)-2,6,6-trimethyl-cyclohex-1-enyl]-propenal 
• 76686-19-6 1-(1-Methoxy-1-methyl-ethoxymethyl)-2,6,6-trimethyl-cyclohexa-1,3-diene 
• 121401-84-1 (E)-3-((S)-4-Hydroxy-2,6,6-trimethyl-cyclohex-1-enyl)-acrylonitrile 
• 4436-51-5 1-hydroxymethyl-2,6,6-trimethylcyclohexa-1,3-diene 
• 116-26-7 safranal 

Downstream Products

• 121521-22-0 (2E,4E,6Z,8E)-9-((S)-4-Hydroxy-2,6,6-trimethyl-cyclohex-1-enyl)-3,7-dimethyl-nona-2,4,6,8-tetraenenitrile 
• 121521-19-5 3S-hydroxy-9-cis-retinal 
• 76686-34-5 (2E,4E,6E,8E)-9-(4-Hydroxy-2,6,6-trimethyl-cyclohex-1-enyl)-3,7-dimethyl-nona-2,4,6,8-tetraenoic acid ethyl ester 
• 115075-58-6 all trans, 13-cis 3-hydroxyretinal 
• 6890-93-3 4-((1E,3E,5E,7E)-9-Hydroxy-3,7-dimethyl-nona-1,3,5,7-tetraenyl)-3,5,5-trimethyl-cyclohex-3-enol 
• 81600-87-5 all trans, 9-cis 3-hydroxyretinal 
• 6890-91-1 (3RS,all-E)-hydroxyretinal 
• 121401-89-6 (2E,4E,6Z,8E)-9-[(S)-4-(tert-Butyl-dimethyl-silanyloxy)-2,6,6-trimethyl-cyclohex-1-enyl]-3,7-dimethyl-nona-2,4,6,8-tetraenenitrile 

Relevant articles and documents

SYNTHESIS OF OPTICALLY ACTIVE 3-DIAZOACETYLRETINALS WITH TRIISOPROPYLPHENYLSULFONYLHYDRAZONE

An improved synthesis of photoaffinity labeled, optically active retinal derivatives is presented.A stable, easy to handle, glyoxalic acid 2,4,6-triisopropylphenylsulfonylhydrazone (TIPPS) reacts with 3-hydroxyretinal to give the diazoacetylretinal analog in satisfactory yield.