121670-79-9Relevant articles and documents
Reactions of 1H-1,2- and 1H-1,3-Diazepines with Dimethyl Acetylenedicarboxylate
Kurita, Jyoji,Kakusawa, Naoki,Tsuchiya, Takashi
, p. 1880 - 1881 (1987)
The title reactions yield the 3a,7a-dihydropyrrolopyridines (2) and 3a,7a-dihydroindazoles (9), respectively, probably via the diazonine intermediates (4) and (8) derived from the initially formed ? cycloadducts; the indazoles (9) further react with the reagent to give the dimethyl phthalates (6) and the pyrazoles (7) via the ? cycloadducts (10).