121809-01-6

Basic information

• Product Name: (-)-3-(7'-Benzyloxymethyl-bicyclo<2.2.1>hept-5'-ene-2'-carbonyl)-1,3-oxazolin-2-one
• Synonyms: (-)-3-(7'-Benzyloxymethyl-bicyclo<2.2.1>hept-5'-ene-2'-carbonyl)-1,3-oxazolin-2-one
• CAS NO: 121809-01-6
• Molecular Weight: 327.38
• Mol File: 121809-01-6.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (-)-3-(7'-Benzyloxymethyl-bicyclo<2.2.1>hept-5'-ene-2'-carbonyl)-1,3-oxazolin-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (-)-3-(7'-Benzyloxymethyl-bicyclo<2.2.1>hept-5'-ene-2'-carbonyl)-1,3-oxazolin-2-one(121809-01-6)
• EPA Substance Registry System: (-)-3-(7'-Benzyloxymethyl-bicyclo<2.2.1>hept-5'-ene-2'-carbonyl)-1,3-oxazolin-2-one(121809-01-6)

Safety Data

• Hazardous Substances Data: 121809-01-6(Hazardous Substances Data)

Upstream product

• 39939-07-6 5-(benzyloxymethyl)cyclopentadiene 
• 2043-21-2 acryloyl-1,3-oxazolidin-2-one 

Downstream Products

• 139108-84-2 (1R,2R,4S,7R)-7-Benzyloxymethyl-2-methylsulfanyl-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid ethyl ester 
• 115219-37-9 Ethyl 7-Benzyloxymethylbicyclo<2.2.1>hept-5-ene-2-endo-carboxylate 
• 139108-82-0 7-Benzyloxymethyl-2-methylthiobicyclo<2.2.1>hept-5-ene-2-carboxylic Acid 
• 53153-20-1 (1R,4S,7R)-(-)-bicyclo <2.2.1> hept-7-benzyloxymethyl-5-ene-2-one 
• 115219-35-7 (1R,2S,4S,7R)-7-Benzyloxymethyl-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid 

Relevant articles and documents

First example of a highly enantioselective catalytic Diels-Alder reaction of an achiral C2v-symmetric dienophile and an achiral diene

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Evidence for the importance of π-π attractive interactions in enantioselective Diels-Alder reactions chiral catalysts of type (RO)2TiCl2

Reaction of diol 4 with Ti(O i-Pr)4 followed by SiCl4 results in formation of the Ti (IV) complex 5 which is an exceptionally effective catalyst for enantioselective Diels-Alder reactions. The origin of the high enantioselectivities