122098-09-3Relevant articles and documents
Heterocyclization of compounds containing diazo and cyano groups. 6. Theoretical and experimental investigations of cyclization of 2-cyano-2-diazoacetamides to 5-hydroxy-1,2,3-triazole-4-carbonitriles
Morzherin,Kolobov,Mokrushin,Brauer,Anders,Bakulev
, p. 22 - 36 (2007/10/03)
A series of N-alkyl- and N-aryl-2-cyano-2-diazoacetamides was synthesized by the reaction of 2-amino-2-cyanoacetamides with sodium nitrite in hydrochloric acid. The mechanism of their heteroelectrocyclization to 5-hydroxy-1,2,3-triazoles was investigated