1227188-09-1Relevant articles and documents
Palladium-catalyzed synthesis of carbazoles from N-(2-halophenyl)-2,6-diisopropylanilines via C-C cleavage
Chianese, Anthony R.,Rogers, Scott L.,Al-Gattas, Hanna
supporting information; experimental part, p. 2241 - 2243 (2010/05/18)
The synthesis of 1-isopropyl-substituted carbazoles by the palladium-catalyzed dealkylative cyclization of N-(2-halophenyl)-2,6-diisopropylanilines is described. The reaction involves intramolecular C-C bond formation, coupled with the cleavage of a C-X bond and a C-C bond, and is proposed to proceed through the formation of a dearomatized intermediate.