123196-48-5

Basic information

• Product Name: (+)-(4R)-2,2-Dimethyl-4-tetrahydropyranyloxy-1-cyclohexanone
• CAS NO: 123196-48-5
• Molecular Weight: 226.316
• Mol File: 123196-48-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (+)-(4R)-2,2-Dimethyl-4-tetrahydropyranyloxy-1-cyclohexanone(CAS DataBase Reference)
• NIST Chemistry Reference: (+)-(4R)-2,2-Dimethyl-4-tetrahydropyranyloxy-1-cyclohexanone(123196-48-5)
• EPA Substance Registry System: (+)-(4R)-2,2-Dimethyl-4-tetrahydropyranyloxy-1-cyclohexanone(123196-48-5)

Safety Data

• Hazardous Substances Data: 123196-48-5(Hazardous Substances Data)

Upstream product

• 110-87-2 3,4-dihydro-2H-pyran 
• 131319-96-5 (+)-(R)-4-Hydroxy-2,2-dimethyl-1-cyclohexanone 
• 123196-48-5 (+/-)-2,2-Dimethyl-4-tetrahydropyranyloxy-1-cyclohexanone 
• 123214-39-1 (+/-)-4-Hydroxy-2,2-dimethyl-1-cyclohexanone 
• 76451-81-5 (+/-)-2,2-Dimethyl-4,4-ethylenedioxy-1-cyclohexanol 
• 131206-75-2 3,3-Dimethyl-4,4-ethylenedioxy-1-cyclohexanone 
• 1193-47-1 2,2-dimethyl-cyclohexanone 
• 131319-94-3 (-)-(S)-4-Hydroxy-2,2-dimethyl-1-cyclohexanone 
• 60739-53-9 4-(tetrahydro-2H-pyran-2-yloxy)cyclohexanone 
• 74-88-4 methyl iodide 

Downstream Products

• 123214-39-1 (+/-)-4-Hydroxy-2,2-dimethyl-1-cyclohexanone 
• 103532-78-1 (-)-(S)-2,2-Dimethyl-1-cyclohexanol 
• 131206-73-0 (+)-(S)-4-Hydroxy-3,3-Dimethyl-1-cyclohexanone 
• 131206-72-9 2,2-Dimethylcyclohexane-1,4-dione 
• 76686-09-4 (+)-(R)-4-Hydroxy-2,6,6-trimethyl-2-cyclohexen-1-one 
• 131206-71-8 (+/-)-4-Oxo-3,3-dimethyl-1-cyclohexyl acetate 
• 41703-33-7 (S)-2,2,6-Trimethyl-4-(tetrahydro-pyran-2-yloxy)-cyclohexanone 
• 131319-96-5 (+)-(R)-4-Hydroxy-2,2-dimethyl-1-cyclohexanone 
• 131319-94-3 (-)-(S)-4-Hydroxy-2,2-dimethyl-1-cyclohexanone 
• 123196-48-5 (S)-2,2-Dimethyl-4-(tetrahydro-pyran-2-yloxy)-cyclohexanone 
• 6901-90-2 (S)-methyl abscisate 
• 123214-38-0 (+)-(S)-2,2-Dimethyl-6-methylene-4-tetrahydropyranyloxy-1-cyclohexanone 
• 123196-51-0 (+)-(1'S,4'S)-(2Z,4E)-5-(1',4'-Diydroxy-2',2'-dimethyl-6'-methylenecyclohexyl)-3-methyl-2,5-pentadien-1-ol 
• 123196-53-2 (2Z,4E)-5-((1S,4S)-1,4-Dihydroxy-2,2-dimethyl-6-methylene-cyclohexyl)-3-methyl-penta-2,4-dienal 

Relevant articles and documents

Enzymatic Preparation of Chiral 4-Hydroxy-2,2-dimethyl-1-cyclohexanone as a Chiral Building Block

(S)-4-Hydroxy-2,2-dimethyl-1-cyclohexanone (1a) was prepared by two enzymatic methods. 1,4-Cyclohexanediol was converted to monoacetal (11) via (+/-)-1a.Enzymatic reduction of 11 by baker's yeast gave (S)-1 of almost 100 percent e.e.Direct hydroxylation of 2,2-dimethyl-1-cyclohexanone (14) by P-450 camphor monooxygenase of the cloned genes of Pseudomonas putida PpG1 gave (S)-1a of almost 100 percent e.e., too.According to Mitsunobu's method, SN-2 inversion of (S)-1 gave (R)-1.

Synthesis of (+/-)-(2Z,4E)-trans-1',4'-Dihydroxy-γ-ionylideneacetic Acid, a Fungal Biosynthetic Intermediate of Abscisic Acid

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