1232578-70-9

Basic information

• Product Name: ethyl 4-(2-(naphthalen-2-yl)-2-oxoethyl)benzoate
• Synonyms: ethyl 4-(2-(naphthalen-2-yl)-2-oxoethyl)benzoate
• CAS NO: 1232578-70-9
• Molecular Weight: 318.372
• Mol File: 1232578-70-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: ethyl 4-(2-(naphthalen-2-yl)-2-oxoethyl)benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 4-(2-(naphthalen-2-yl)-2-oxoethyl)benzoate(1232578-70-9)
• EPA Substance Registry System: ethyl 4-(2-(naphthalen-2-yl)-2-oxoethyl)benzoate(1232578-70-9)

Safety Data

• Hazardous Substances Data: 1232578-70-9(Hazardous Substances Data)

Upstream product

• 13298-50-5 1-methyl-3-(2-naphthyl)propane-1,3-dione 
• 51934-41-9 4-iodobenzoic acid ethyl ester 

Relevant articles and documents

Copper catalyzed arylation/C-C bond activation: An approach toward α-aryl ketones

An efficient arylation/C-C activation process was discovered. -Diketones with aryl halides (aryl iodides and aryl bromides) could undergo reaction smoothly in the presence of Cu(I) or Cu(II) salts in DMSO using K3 PO4 3H2 O without ligands. The role of H2 O was unprecedented, which assisted the C-C activation. Various -aryl ketones could be efficiently synthesized by this novel method. In situ monitoring of the formation of KOAc and experimentation relating to "a classic diagnostic technique for the participation of radical anion intermediates" revealed the preliminary mechanistic information for the reaction. This method is simple, general, and practical which complemented the classic method for the rapid construction of C-C bonds to a carbonyl moiety.