1233766-64-7

Basic information

• Product Name: cis-[Pt(κ2S,O-2,6-F2C6H3C(O)NC(S)NEt2)(1,10-phenanthroline)]PF6
• CAS NO: 1233766-64-7
• Molecular Weight: 791.564
• Mol File: 1233766-64-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: cis-[Pt(κ2S,O-2,6-F2C6H3C(O)NC(S)NEt2)(1,10-phenanthroline)]PF6(CAS DataBase Reference)
• NIST Chemistry Reference: cis-[Pt(κ2S,O-2,6-F2C6H3C(O)NC(S)NEt2)(1,10-phenanthroline)]PF6(1233766-64-7)
• EPA Substance Registry System: cis-[Pt(κ2S,O-2,6-F2C6H3C(O)NC(S)NEt2)(1,10-phenanthroline)]PF6(1233766-64-7)

Safety Data

• Hazardous Substances Data: 1233766-64-7(Hazardous Substances Data)

Upstream product

• 18432-95-6 dichloro(1,10-phenanthroline)platinum(II) 
• 1196586-76-1 N-(diethylcarbamothioyl)-2,6-difluorobenzamide 

Relevant articles and documents

Cationic palladium(II), platinum(II) and ruthenium(II) complexes containing a chelating difluoro-substituted thiourea ligand

The fluorine substituted thiourea 2,6-F2C6H3C(O)NHC(S)NEt2 was prepared in good yield from the reaction of 2,6-F2C6H3C(O)Cl with KSCN and Et2NH in acetone. Using this compound several heteroleptic, monocationic Pd(II), Pt(II) and Ru(II) complexes of the type cis-[M{κ2S,O-2,6-F2C6H3C(O)NC(S)NEt2}(L)]PF6 [M = Pt, Pd; L = (Ph3P)2, tBu2bipy, 1,10-phen] as well as [Ru(η6-p-cym){κ2S,O-2,6-F2C6H3C(O)NC(S)NEt2}(PPh3)]PF6 were prepared in high yields. The compounds were characterised by spectroscopic methods and, in one case, by single crystal X-ray diffraction.