1236046-65-3Relevant articles and documents
Pyridine-directed carbon–carbon single bond activation: Rhodium-catalyzed decarbonylation of aryl and heteroaromatic ketones
Johnson, Jeffrey B.,Salisbury, Eric A.,Schoonover, Erik J.,VanderRoest, Jacob P.,Wagner, Cole J.
supporting information, (2021/07/28)
The decarbonylation of 2-pyridyl-substituted ketones via transition metal-catalyzed carbon–carbon bond activation provides ready access to a variety of biaryl compounds. The highly efficient and general method provides reliable decarbonylation of benzophenones including a range of functional groups and substitution patterns. The methodology has also proven highly efficient for heteroaromatic substrates, including those containing thiophenyl, indolyl, quinolinyl, and pyridine substitution.
Arylmethyl chlorides: New bifunctional reagents for palladium-catalyzed ortho -chlorination and acylation of 2-arylpyridines
Zhang, Guodong,Sun, Suyan,Yang, Fan,Zhang, Qian,Kang, Jianxun,Wu, Yusheng,Wu, Yangjie
, p. 443 - 450 (2015/02/19)
A chemoselective, palladium-catalyzed, ligand-directed ortho-C-H chlorination and acylation process has been developed, exhibiting high regioselectivity for 2-arylpyridines bearing a meta-substituent. Worthy of note is the fact that arylmethyl chlorides a
Decarboxylative acylation of arenes with α-oxocarboxylic acids via palladium-catalyzed C-H activation
Li, Mingzong,Ge, Haibo
supporting information; experimental part, p. 3464 - 3467 (2010/10/01)
(Equation Presented). An efficient palladium-catalyzed decarboxylative acylation of unactivated arenes with α-oxocarboxylic acids is reported. This method provides a novel access to aryl ketones.
