1246788-84-0Relevant articles and documents
Rapid and slow generation of 1-trifluoromethylvinyllithium: syntheses and applications of CF3-containing allylic alcohols, allylic amines, and vinyl ketones
Nadano, Ryo,Fuchibe, Kohei,Ikeda, Masahiro,Takahashi, Hiroki,Ichikawa, Junji
, p. 1875 - 1883 (2011/04/22)
1-(Trifluoromethyl)vinylation is accomplished in two protocols by the in situ generation of thermally unstable 3,3,3-trifluoroprop-1-en-2-yllithium (1):1) a rapid lithium-halogen-exchange reaction of 2-bromo-3,3,3-trifluoroprop- 1-ene (2) takes effect wit