14633-65-9Relevant articles and documents
A facile access for multisubstituted trifluoromethyl olefins by visible light catalysis
Ren, Shujian,Fu, Jiahui,Cheng, Dongping,Li, Xiaonian,Xu, Xiaoliang
supporting information, (2021/02/09)
Induced by visible light, a green approach for the highly substituted trifluoromethyl olefins has been developed by using alkyl boronic acid as a carbon radical precursor and the Boc-modified trifluoromethylated Baylis-Hillman adduct (BMTBHA) as an accept
Flash generation of α-(trifluoromethyl)vinyllithium and application to continuous flow three-component synthesis of α-trifluoromethylamides
Nagaki, Aiichiro,Tokuoka, Shinya,Yoshida, Jun-Ichi
supporting information, p. 15079 - 15081 (2014/12/11)
α-(Trifluoromethyl)vinyllithium was generated and used for the reaction with electrophiles at -78 °C in a flow microreactor although the batch reaction should be carried out at ca. -100°C, and the method was applied to continuous flow three-component synt
Rapid and slow generation of 1-trifluoromethylvinyllithium: syntheses and applications of CF3-containing allylic alcohols, allylic amines, and vinyl ketones
Nadano, Ryo,Fuchibe, Kohei,Ikeda, Masahiro,Takahashi, Hiroki,Ichikawa, Junji
experimental part, p. 1875 - 1883 (2011/04/22)
1-(Trifluoromethyl)vinylation is accomplished in two protocols by the in situ generation of thermally unstable 3,3,3-trifluoroprop-1-en-2-yllithium (1):1) a rapid lithium-halogen-exchange reaction of 2-bromo-3,3,3-trifluoroprop- 1-ene (2) takes effect wit
