125424-02-4

Basic information

• Product Name: 2-[(1R,2R,5R)-2-Hydroxy-2,6,6-trimethyl-bicyclo[3.1.1]hept-(3E)-ylideneamino]-pent-4-enoic acid (1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl ester
• CAS NO: 125424-02-4
• Molecular Weight: 403.605
• Mol File: 125424-02-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-[(1R,2R,5R)-2-Hydroxy-2,6,6-trimethyl-bicyclo[3.1.1]hept-(3E)-ylideneamino]-pent-4-enoic acid (1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 2-[(1R,2R,5R)-2-Hydroxy-2,6,6-trimethyl-bicyclo[3.1.1]hept-(3E)-ylideneamino]-pent-4-enoic acid (1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl ester(125424-02-4)
• EPA Substance Registry System: 2-[(1R,2R,5R)-2-Hydroxy-2,6,6-trimethyl-bicyclo[3.1.1]hept-(3E)-ylideneamino]-pent-4-enoic acid (1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl ester(125424-02-4)

Safety Data

• Hazardous Substances Data: 125424-02-4(Hazardous Substances Data)

Upstream product

• 1845-25-6 (1S,2S,5S)-(-)-2-hydroxypinan-3-one 
• 1845-25-6 (-)-(2R,3R,5R)-2-hydroxy-3-pinanone 
• 120143-37-5 (1S,3S,4R)-menthyl glycinate 
• 106-95-6 allyl bromide 
• 125423-98-5 [(1R,2R,5R)-2-Hydroxy-2,6,6-trimethyl-bicyclo[3.1.1]hept-(3E)-ylideneamino]-acetic acid (1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl ester 
• 63254-60-4 (1R,2S,5R)-2-isopropyl-5-methylcyclohexyl 2-aminoacetate 
• 125423-98-5 [(1R,2R,5R)-2-Hydroxy-2,6,6-trimethyl-bicyclo[3.1.1]hept-(3E)-ylideneamino]-acetic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester 
• 125423-98-5 [(1S,2S,5S)-2-Hydroxy-2,6,6-trimethyl-bicyclo[3.1.1]hept-(3E)-ylideneamino]-acetic acid (1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl ester 
• 125423-98-5 [(1S,2S,5S)-2-Hydroxy-2,6,6-trimethyl-bicyclo[3.1.1]hept-(3E)-ylideneamino]-acetic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester 

Downstream Products

• 54594-06-8 D-allylglycine 
• 16338-48-0 L-allylglycine 

Relevant articles and documents

ASYMMETRIC SYNTHESIS VII: DOUBLE STEREODIFFERENTATION IN ALLYLYTION OF KETIMINES BEARING TWO CHIRAL AUXILIARIES. APPLICATION TO ENANTIOSELECTIVE SYNTHESIS OF α-ALLYLGLYCINE

A diuble asymmetric induction has been observed in allylation of the imines derived from (+)-camphor, (+)- and (-)-2-hydroxypinan-3-ones with (+)- and (-)-menthyl glycinates.After hydrolysis of the allylated intermediates, (R)- and (S)-α-allylglycines are obtained in 3-90percent optical yields.