1256640-08-0

Basic information

• Product Name: C₂HF₃O₂*C₁₃H₁₉NO₂
• Synonyms: C₂HF₃O₂*C₁₃H₁₉NO₂
• CAS NO: 1256640-08-0
• Molecular Weight: 335.323
• Mol File: 1256640-08-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₂HF₃O₂*C₁₃H₁₉NO₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₂HF₃O₂*C₁₃H₁₉NO₂(1256640-08-0)
• EPA Substance Registry System: C₂HF₃O₂*C₁₃H₁₉NO₂(1256640-08-0)

Safety Data

• Hazardous Substances Data: 1256640-08-0(Hazardous Substances Data)

Upstream product

• 112924-08-0 tert-butyl N-(benzyloxycarbonyl)-D-phenylalaninate 
• 2448-45-5 Cbz-D-Phe 
• 3081-28-5 D-phenylalanine tert-butyl ester 
• 76-05-1 trifluoroacetic acid 
• 673-06-3 D-(R)-phenylalanine 

Relevant articles and documents

A bismuth(III)-catalyzed friedel-crafts cyclization and stereocontrolled organocatalytic approach to (-)-platensimycin

A high yielding route to the (-)-platensimycin core is communicated. This entailed the discovery of Bi(OTf)3 to catalyze a Friedel-Crafts cyclization of a free lactol, supplemented by LiClO4 to suppress the Lewis basicity of the sulfonate group. After TBAF-promoted cyclodearomatization, a diastereoselective conjugate reduction of a dienone was achieved by adopting amine-based organocatalytic rationales to reverse the inherent steric control of the substrate.