127419-28-7

Basic information

• Product Name: Pt((HC₆F₄)NCH₂CH₂N(CH₃)2)Cl(C₅H₅N)
• CAS NO: 127419-28-7
• Molecular Weight: 544.839
• Mol File: 127419-28-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Pt((HC₆F₄)NCH₂CH₂N(CH₃)2)Cl(C₅H₅N)(CAS DataBase Reference)
• NIST Chemistry Reference: Pt((HC₆F₄)NCH₂CH₂N(CH₃)2)Cl(C₅H₅N)(127419-28-7)
• EPA Substance Registry System: Pt((HC₆F₄)NCH₂CH₂N(CH₃)2)Cl(C₅H₅N)(127419-28-7)

Safety Data

• Hazardous Substances Data: 127419-28-7(Hazardous Substances Data)

Upstream product

• 110-86-1 pyridine 
• 68558-86-1 thallium(I) pentafluorobenzoate 
• 41575-66-0 (SP-4-3)-dichlorido(N,N-dimethyl-ethane-1,2-diamine)platinum(II) 

Relevant articles and documents

Organoamidometallics. II. Decarboxylation Syntheses and Structures of platinum(II) Complexes

The complexes (L = py, X = Cl or Br; L = 2-methylpyridine or 4-methylpyridine, X = Cl) have been prepared by decarboxylation reactions between PtX2(dmen) (dmen = N,N-dimethylethane-1,2-diamine) and thallous pentafluorobenzoate in the appropriate hot pyridine.Other organoamidoplatinum(II) complexes, (R = p-HC6F4, X = I; R = C6F5, X = Cl, Br or I; R = p-MeC6F4, X = Cl; R = p-ClC6F4 or p-BrC6F4, X = I) and (R = p-HC6F4; dmpy = 2,5-dimethylpyridine), have been prepared by analogous decarboxylations between PtX2(dmen), thallous 2,3,5,6-tetrafluorobenzoate, and the corresponding polyfluorobenzene, RF.The mixed halogen complex has been prepared similarly and the crystal structure determined.This shows square-planar stereochemistry with the halogen and pyridine trans to NC6F5 and NMe2 respectively.Comparison of spectroscopic data suggests the other complexes have similar stereochemistry.