1274906-16-9

Basic information

• Product Name: N-(6-(tert-butyldimethylsilyloxy)-1-(2-oxooxazolidin-3-yl)hex-2-enylidene)-4-methylbenzenesulfonamide
• CAS NO: 1274906-16-9
• Molecular Weight: 466.674
• Mol File: 1274906-16-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-(6-(tert-butyldimethylsilyloxy)-1-(2-oxooxazolidin-3-yl)hex-2-enylidene)-4-methylbenzenesulfonamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(6-(tert-butyldimethylsilyloxy)-1-(2-oxooxazolidin-3-yl)hex-2-enylidene)-4-methylbenzenesulfonamide(1274906-16-9)
• EPA Substance Registry System: N-(6-(tert-butyldimethylsilyloxy)-1-(2-oxooxazolidin-3-yl)hex-2-enylidene)-4-methylbenzenesulfonamide(1274906-16-9)

Safety Data

• Hazardous Substances Data: 1274906-16-9(Hazardous Substances Data)

Upstream product

• 98-59-9 p-toluenesulfonyl chloride 
• 124696-14-6 [(6-bromohex-5-yn-1-yl)oxy](tert-butyl)dimethylsilane 
• 70-55-3 toluene-4-sulfonamide 
• 1246242-14-7 3-[6-(tert-butyldimethylsilanyloxy)hex-1-ynyl]oxazolidin-2-one 
• 242461-31-0 [N-(p-toluenesulfonyl)imino](2-tert-butylsulfonyl)phenyliodinane 
• 99879-61-5 2-Methyl-N-tosyl-pyridinium-imid 
• 40949-56-2 N-(p-toluenesulphonylimino)pyridinium ylide 
• 71996-32-2 N-(5λ⁴-dibenzo[b,d]thiophen-5-ylidene)-4-methylbenzenesulfonamide 
• 1274906-15-8 C₁₇H₁₆N₂O₂S 
• 1274906-14-7 N-(3,5-dichloro-1-pyridylidene)-4-methyl-benzenesulfonamide 
• 1274906-13-6 C₁₄H₁₄N₂O₃S 

Relevant articles and documents

Gold-catalyzed nitrene transfer to activated alkynes: Formation of α,β-unsaturated amidines

A gold-catalyzed intermolecular nitrene transfer to alkynes was developed for the first time, revealing a new mode of nitrene transfer and providing a novel access to versatile α-imino metal carbenes. Various mild nitrene-transfer reagents were examined, and iminopyridium ylides especially those based on 3,5-dichloropyridine proved be highly effective. With activated alkynes such as N-alkynyloxazolidinones as substrates, α,β- unsaturated amidines were formed in mostly good yields.