1274906-21-6

Basic information

• Product Name: 3-[3-(benzyloxy)prop-1-yn-1-yl]-1,3-oxazolidin-2-one
• Synonyms: 3-[3-(benzyloxy)prop-1-yn-1-yl]-1,3-oxazolidin-2-one
• CAS NO: 1274906-21-6
• Molecular Weight: 231.251
• Mol File: 1274906-21-6.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 3-[3-(benzyloxy)prop-1-yn-1-yl]-1,3-oxazolidin-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: 3-[3-(benzyloxy)prop-1-yn-1-yl]-1,3-oxazolidin-2-one(1274906-21-6)
• EPA Substance Registry System: 3-[3-(benzyloxy)prop-1-yn-1-yl]-1,3-oxazolidin-2-one(1274906-21-6)

Safety Data

• Hazardous Substances Data: 1274906-21-6(Hazardous Substances Data)

Upstream product

• 497-25-6 dimethylenecyclourethane 
• 4039-82-1 Benzyl propargyl ether 
• 218431-34-6 (((3-bromoprop-2-yn-1-yl)oxy)methyl)benzene 

Downstream Products

• 1274906-28-3 N-(3-(benzyloxy)-1-(2-oxooxazolidin-3-yl)allylidene)-4-methylbenzenesulfonamide 
• 2043-21-2 acryloyl-1,3-oxazolidin-2-one 

Relevant articles and documents

On the formation of seven-membered rings by arene-ynamide cyclization

Abstract: A Br?nsted acid-catalyzed selective arene-ynamide cyclization is described. This reaction proceeds via a keteniminium intermediate and enables the preparation of seven-membered ring enamide products. Mechanistic studies uncover an unusual product inhibition behavior. Graphical abstract: [Figure not available: see fulltext.].

N-Substitution dependent stereoselectivity switch in palladium catalyzed hydroalkynylation of ynamides: A regio and stereoselective synthesis of ynenamides

A highly general palladium catalysed regioselective hydroalkynylation of ynamides for versatile enamide building blocks with an alkyne tether is achieved with an N-substitution dependent stereoselectivity switch under very mild reaction conditions.