127492-01-7Relevant articles and documents
Lewis acid-promoted, stereocontroiled, gram scale, diels-alder cycloadditions of electronically matched 2-pyrones and vinyl ethers: The critical importance of molecular sieves and the temperature of titanium coordination with the pyrone
Posner, Gary H.,Dai, Haiyan,Bull, D. Scott,Lee, Jae-Kyoo,Eydoux, Franck,Ishihara, Yuji,Welsh, William,Pryor, Neil,Petr Jr., Stan
, p. 671 - 676 (2007/10/03)
(R)-(+)-Binol-titanium coordinates with commercial methyl 2-pyrone-3-carboxylate and promotes mild, highly enantiocontrolled Diels-Alder cycloadditions with electron-rich vinyl ether CH2=CHOCH2-1-naphthyl and vinyl silyl ether CHsub
A New and Efficient Asymmetric Synthesis of an A-Ring Precursor to Physiologically Active 1α-Hydroxyvitamin D3 Steroids
Posner, Gary H.,Carry, Jean-Christophe,Anjeh, Tizah E. N.,French, Andrew N.
, p. 7012 - 7014 (2007/10/02)
A highly stereocontrolled and mild Diels-Alder cycloaddition involving stereochemically matched pyrone (S)-lactate 4 and Lewis acid (-)-Pr(hfc)3 produced bicyclic lactone endo-5 via a double stereodifferentiation process.Bicyclic lactone 5 was then transf