127591-24-6

Basic information

• Product Name: p-methoxyphenyl(triphenylphosphine)gold(I)
• Synonyms: p-methoxyphenyl(triphenylphosphine)gold(I)
• CAS NO: 127591-24-6
• Molecular Weight: 566.389
• Mol File: 127591-24-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: p-methoxyphenyl(triphenylphosphine)gold(I)(CAS DataBase Reference)
• NIST Chemistry Reference: p-methoxyphenyl(triphenylphosphine)gold(I)(127591-24-6)
• EPA Substance Registry System: p-methoxyphenyl(triphenylphosphine)gold(I)(127591-24-6)

Safety Data

• Hazardous Substances Data: 127591-24-6(Hazardous Substances Data)

Upstream product

• 14243-64-2 (triphenylphosphine)gold(I) chloride 
• 5720-07-0 4-methoxyphenylboronic acid 
• 13139-86-1 4-methoxyphenyl magnesium bromide 

Downstream Products

• 1130440-56-0 (CH₃O₂C)(C₆H₄OCH₃)CC(O₂CCH₃)(Au(P(C₆H₅)3)) 
• 21209-78-9 iodo(triphenylphosphine)gold(I) 
• 5957-90-4 4-(2-pyridinyl)anisole 
• 108030-81-5 2-(4-methoxyphenyl)pyrazine 
• 52988-34-8 4-(4'-methoxyphenyl)benzaldehyde 
• 3218-36-8 4-Phenylbenzaldehyde 
• 2132-80-1 4,4'-Dimethoxybiphenyl 
• 90035-34-0 4-(4-trifluoromethylphenyl)benzaldehyde 
• 25679-28-1 cis-Anethole 
• 4180-23-8 E-1-(4'-methoxyphenyl)prop-1-ene 
• 51507-22-3 (Z)-ethyl 3-(4-methoxyphenyl)acrylate 
• 58743-77-4 4'-methoxybiphenyl-4-carbonitrile 
• 7440-57-5 gold 
• 1284294-09-2 Cp(*)Rh(chloride)(triphenylphosphine)(C₆H₄OMe) 

Relevant articles and documents

Mechanochemical synthesis of (hetero)aryl Au(i) complexes

Growing demand for sustainable chemical syntheses casts mechanochemistry in a new light as an environmentally benign alternative to traditional solvent-based methods. Given recent interest in Au(i) complexes for catalytic, materials, and medicinal applications, we developed a mechanochemical protocol to prepare (hetero)aryl Au(i) complexes under green conditions. The procedure reported here uses C-H or C-B activation to afford the corresponding Au(i) complexes in high yields. Our approach bypasses external heating, long reaction times and the use of toxic solvents. We demonstrate that mechanochemical C-H auration can be used on highly functionalised bioactive substrates. Mechanistic aspects of the C-H auration are discussed.

Organogold(I) complexes: Synthesis, X-ray crystal structures and aurophilicity

The synthesis of RAuPPh3 (R = aryl) from ClAuPPh3 and Grignard RM reagents (M = Li or MgX) is described. New (vinylphenyl)gold(I) and other arylgold(I) complexes were characterized by 1H, 13C, 31P, s