128473-03-0

Basic information

• Product Name: dibenzyl 2,3,4-tri-O-acetyl-α-L-fucopyranosyl phosphate
• Synonyms: dibenzyl 2,3,4-tri-O-acetyl-α-L-fucopyranosyl phosphate
• CAS NO: 128473-03-0
• Molecular Weight: 550.499
• Mol File: 128473-03-0.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: dibenzyl 2,3,4-tri-O-acetyl-α-L-fucopyranosyl phosphate(CAS DataBase Reference)
• NIST Chemistry Reference: dibenzyl 2,3,4-tri-O-acetyl-α-L-fucopyranosyl phosphate(128473-03-0)
• EPA Substance Registry System: dibenzyl 2,3,4-tri-O-acetyl-α-L-fucopyranosyl phosphate(128473-03-0)

Safety Data

• Hazardous Substances Data: 128473-03-0(Hazardous Substances Data)

Upstream product

• 64913-16-2 L-fucose tetraacetate 
• 140111-07-5 dibenzyl 2,3,4-tri-O-acetyl-α-L-fucosyl phosphite 
• 7404-35-5 1,2,3,4-tetra-O-acetyl-L-fucopyranose 
• 73-34-7 6-deoxy-L-galactose 
• 149717-37-3 Acetic acid (3S,4R,5R,6S)-4,5-diacetoxy-2-(bis-benzyloxy-phosphanyloxy)-6-methyl-tetrahydro-pyran-3-yl ester 
• 1623-08-1 phosphoric acid dibenzyl ester 
• 128571-86-8 2,3,4-tri-O-acetyl-α-L-fucopyranosyl trichloroacetimidate 
• 16741-27-8 2,3,4-tri-O-acetyl-α-L-fucopyranosyl bromide 
• 119095-47-5 triethylammonium dibenzyl phosphate 

Downstream Products

• 30174-43-7 uridine 5-(α-L-fucopyranosyl) diphosphate 

Relevant articles and documents

Large-scale synthesis of β-L-fucopyranosyl phosphate and the preparation of GDP-β-L-fucose

A practical 15-mmol large-scale synthesis of β-L-fucopyranosyl dicyclohexylammonium phosphate from L-fucose in 63percent overall yield was developed.The synthesis took advantage of a neighboring Bz-2 group participating in a Koenigs-Knorr like glycosylati

Process for the stereoselective preparation of β-fucopyranosyl phosphates and very pure GDP-fucose

The invention relates to a process for the stereoselective preparation of β-L-fucopyranosyl phosphates via the trichloroacetimidates of protected L-fucose and the synthesis and purification of very pure GDP-fucose from the β-L-fucopyranosyl phosphates.

Glycosyl Imidates, 47. Stereospecific Synthesis of α- and β-L-Fucopyranosyl Phosphates and of GDP-Fucose via Trichloroacetimidate

Reaction of the benzyl- and acetyl-protected α-trichloroacetimidates 1 and 6α with dialkyl and diaryl phosphates in the presence of traces of acid affords stereoselectively the thermodynamically more stable α-L-fucopyranosyl phosphates 2, 7 and 8, respect