129041-31-2

Basic information

• Product Name: N,N-BIS(3-CHLOROBENZYL)AMINE
• Synonyms: BIS(3-CHLOROBENZYL)AMINE;N,N-BIS(3-CHLOROBENZYL)AMINE
• CAS NO: 129041-31-2
• Molecular Formula: C₁₄H₁₃Cl₂N
• Molecular Weight: 266.17
• EINECS: 932-512-3
• Mol File: 129041-31-2.mol
• Article Data: 13

Chemical Properties

• Boiling Point: 362.2°C at 760 mmHg
• Flash Point: 172.8°C
• Appearance: /
• Density: 1.234g/cm³
• Vapor Pressure: 1.97E-05mmHg at 25°C
• Refractive Index: 1.5880 to 1.5910
• CAS DataBase Reference: N,N-BIS(3-CHLOROBENZYL)AMINE(CAS DataBase Reference)
• NIST Chemistry Reference: N,N-BIS(3-CHLOROBENZYL)AMINE(129041-31-2)
• EPA Substance Registry System: N,N-BIS(3-CHLOROBENZYL)AMINE(129041-31-2)

Safety Data

• Statements: 36/37/38
• Safety Statements: 26-36
• Hazardous Substances Data: 129041-31-2(Hazardous Substances Data)

Usage

General Description

N,N-bis(3-chlorobenzyl)amine is a chemical compound that consists of a central amine group attached to two 3-chlorobenzyl groups. It is commonly used as an intermediate in the production of various pharmaceuticals and organic compounds. This chemical has been found to possess antimicrobial and antioxidant properties, making it a potential candidate for use in the development of new drugs and medications. However, it is important to handle this compound with caution, as it is considered to be toxic and can cause irritation to the skin, eyes, and respiratory system upon exposure. Additionally, it is important to carefully follow safety guidelines and procedures when working with N,N-bis(3-chlorobenzyl)amine to minimize any potential risks to health and safety.

InChI:InChI=1/C14H13Cl2N/c15-13-5-1-3-11(7-13)9-17-10-12-4-2-6-14(16)8-12/h1-8,17H,9-10H2

Upstream product

• 766-84-7 3-chloro-benzonitrile 
• 41097-39-6 3-chlorobenzaldehyde N-[-(3-chlorophenyl)methylidene]hydrazone 
• 108-88-3 toluene 
• 161723-68-8 N-(3-chlorobenzylidene)-1-(3-chlorophenyl)methylamine 
• 64-17-5 ethanol 
• 64-19-7 acetic acid 
• 7647-01-0 hydrogenchloride 
• 861572-96-5 bis-(3-chloro-benzyl)-nitroso-amine 
• 587-04-2 m-Chlorobenzaldehyde 
• 4152-90-3 m-chlorobenzylamine 
• 873-63-2 m-chlorobenzyl alcohol 

Downstream Products

• 1221690-03-4 3-(3-chlorobenzyl)-1H-indole 
• 587-04-2 m-Chlorobenzaldehyde 
• 161723-68-8 N-(3-chlorobenzylidene)-1-(3-chlorophenyl)methylamine 
• 31264-06-9 N-(4-chlorobenzylidene)-4-chlorobenzylamine 

Relevant articles and documents

Switching Selectivity in Copper-Catalyzed Transfer Hydrogenation of Nitriles to Primary Amine-Boranes and Secondary Amines under Mild Conditions

A simple and efficient copper-catalyzed selective transfer hydrogenation of nitriles to primary amine-boranes and secondary amines with an oxazaborolidine-BH3 complex is reported. The selectivity control was achieved under mild conditions by switching the solvent and the copper catalysts. More than 30 primary amine-boranes and 40 secondary amines were synthesized via this strategy in high selectivity and yields of up to 95%. The strategy was applied to the synthesis of 15N labeled in 89% yield.

Surface modification boosts exciton extraction in confined layered structure for selective oxidation reaction

Extracting photogenerated species from bulk to surface is an essential process for gaining efficient semiconductor-based photocatalysis. However, compared with charged photogenerated carriers, neutral exciton exhibits negligible response to electric field. Accordingly, traditional strategies involving band-alignment construction for boosting directional transfer of charge carriers are impracticable for extracting bulk excitons. To this issue, we here propose that the extraction of bulk exciton could be effectively implemented by surface modification. By taking confined layered bismuth oxycarbonate (Bi2O2CO3) as an example, we highlight that the incorporation of iodine atoms on the surface could modify the micro-region electronic structure and hence lead to reduced energy of surface excitonic states. Benefiting from the energy gradient between bulk and surface excitonic states, iodine-modified Bi2O2CO3 possesses high-efficiency bulk exciton extraction, and hence exhibits promoted performance in triggering 1O2-mediated selective oxidation reaction. This work presents the positive role of surface modification in regulating excitonic processes of semiconductor-based photocatalysts. [Figure not available: see fulltext.].

Iron-Catalyzed Intramolecular C-H Amination of α-Azidyl Amides

Iron-catalyzed intramolecular C-H amination of aliphatic azides has recently emerged as a powerful tool for the preparation of nitrogen heterocycles. This paper reports that α-azidyl amides can be converted in high efficacy to imidazolinone compounds via intramolecular C(sp3)-H amination by the action of a simple catalytic system composed of FeCl2 and a β-diketiminate ligand. The reactions provide a simple and atom-economical approach toward polysubstituted imidazolinones.