161723-68-8Relevant articles and documents
A Cu-BTC metal-organic framework (MOF) as an efficient heterogeneous catalyst for the aerobic oxidative synthesis of imines from primary amines under solvent free conditions
Venu, Boosa,Shirisha, Varimalla,Vishali, Bilakanti,Naresh, Gutta,Kishore, Ramineni,Sreedhar, Inkollu,Venugopal, Akula
, p. 5972 - 5979 (2020)
A Cu-BTC (MOF-199) [copper(ii)-benzene-1,3,5-tricarboxylate] catalyst has been synthesized and evaluated for imine synthesis from amine compounds under neat conditions. The performance of the Cu-BTC MOF was significantly higher than that of the CuO supported on Al2O3, TiO2 and SiO2 catalysts. The role of surface Lewis acid sites on the catalyst in the formation of imine products was illustrated by the pyridine-IR studies. The recovered Cu-BTC catalyst demonstrated consistent activity for five cycles under similar experimental conditions. The physicochemical properties of the catalysts were analyzed by XRD, BET-SA, FT-IR, UV-DRS, SEM, TEM, XPS and pyridine adsorbed DRIFT spectroscopy.
Switchable activity of a Ru catalyst bearing an annulated mesoionic carbene ligand for oxidation of primary amines
Bera, Jitendra K.,Din Reshi, Noor U,Pal, Nilay Kumar,Pal, Saikat,Pal, Sourav,Yadav, Suman
, (2022/01/31)
The catalytic activity of a Ru complex 1, bearing a fused π-conjugated imidazo[1,2–a][1,8]naphthyridine-based mesoionic carbene (MIC) ligand, is examined for the oxidation of primary amines. Complex 1 affords nitrile or imine depending on the nature of th
Exciton-Mediated Energy Transfer in Heterojunction Enables Infrared Light Photocatalysis
Jin, Sen,Li, Yuanjin,Liu, Wenxiu,Wang, Hui,Wang, Shuhui,Xie, Yi,Xu, Xiaoliang,Zhang, Xiaodong,Zhao, Zhi
supporting information, p. 12891 - 12896 (2021/05/06)
Although a few semiconductors can directly absorb infrared light, their intrinsic properties like improper band-edge position and strong electron–hole interaction restrict further photocatalytic applications. Herein, we propose an exciton-mediated energy
