129823-42-3Relevant articles and documents
Synthesis of β-nitro ketones from geminal bromonitroalkanes and silyl enol ethers by visible light photoredox catalysis
Cao, Haoying,Ma, Shanshan,Feng, Yanhong,Guo, Yawen,Jiao, Peng
supporting information, p. 1780 - 1783 (2022/02/17)
Various β-nitro ketones, including those bearing a β-tertiary carbon, were prepared from geminal bromonitroalkanes and trimethylsilyl enol ethers of a broad range of ketones by visible light photoredox catalysis, which were then easily converted into β-amino ketones, 1,3-amino alcohols, α,β-unsaturated ketones, β-cyano ketones and γ-nitro ketones.
Catalytic Asymmetric Aldol-Type Reactions Using a Chiral (Acyloxy)borane Complex
Ishihara, Kazuaki,Maruyama, Tohru,Mouri, Makoto,Gao, Qingzhi,Furuta,Kyoji,Yamamoto, Hisashi
, p. 3483 - 3491 (2007/10/02)
In the presence of 20 molpercent of a chiral (acyloxy)borane (CAB) complex prepared from BH3*THF and a chiral mono-O-acylated tartaric acid, achiral silyl enol ethers or ketene silyl acetals react with achiral aldehydes to afford the corresponding aldol-t
HIGHLY SELECTIVE, KINETICALLY CONTROLLED ENOLATE FORMATION USING LITHIUM DIALKYLAMIDES IN THE PRESENCE OF TRIMETHYLCHLOROSILANE
Corey, E. J.,Gross, Andrew W.
, p. 495 - 498 (2007/10/02)
The deprotonation of ketones and esters with lithium dialkylamides in the presence of trimethylchlorosilane leads to enhanced selectivity for the kinetically generated enolate.Lithium t-octyl-t-butylamide is shown to be superior to lithium diisopropylamid
