13027-73-1Relevant articles and documents
Effect of carbenoid structure on the reactivity of rhodium-stabilized carbenoids
Davies, Huw M. L.,Hodges, L. Mark,Matasi, Julius J.,Hansen, Tore,Stafford, Douglas G.
, p. 4417 - 4420 (1998)
The outcome of rhodium(II) pivalate catalyzed decomposition of diaozoacetates in the presence of cyclohexane is highly dependent on carbenoid structure. Carbenoids derived from phenyldiazoacetates or diazoketoesters undergo high yielding intermolecular C-H insertions while other carbenoid systems undergo rearrangements, dimerization or trimerization.
Site-Selective C–H Benzylation of Alkanes with N-Triftosylhydrazones Leading to Alkyl Aromatics
Anderson, Edward A.,Bi, Xihe,Cao, Shanshan,Liu, Zhaohong,Wu, Jiayi,Yi, Fanhua,Yu, Weijie
, p. 2110 - 2124 (2020/08/05)
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Iron-Catalyzed Carbenoid Insertion into C(sp 3)-H Bonds
Cheng, Qing-Qing,Yang, Ji-Min,Xu, Huan,Zhu, Shou-Fei
supporting information, p. 1327 - 1330 (2017/06/27)
An iron-catalyzed carbenoid insertion into C-H bonds of alkanes was developed with high activity (turnover numbers up to 690 in a gram-scale experiment) and chemoselectivity. This non-heme iron-catalyzed C(sp 3)-H insertion reaction provides an efficient strategy for C-H functionalization.
