13064-21-6

Basic information

• Product Name: hepta-1,6-dien-4-ylbenzene
• CAS NO: 13064-21-6
• Molecular Formula: C₁₃H₁₆
• Molecular Weight: 172.2661
• Mol File: 13064-21-6.mol
• Article Data: 12

Chemical Properties

• Boiling Point: 230.6°C at 760 mmHg
• Flash Point: 87.2°C
• Density: 0.88g/cm³
• Vapor Pressure: 0.0991mmHg at 25°C
• Refractive Index: 1.508
• CAS DataBase Reference: hepta-1,6-dien-4-ylbenzene(CAS DataBase Reference)
• NIST Chemistry Reference: hepta-1,6-dien-4-ylbenzene(13064-21-6)
• EPA Substance Registry System: hepta-1,6-dien-4-ylbenzene(13064-21-6)

Safety Data

• Hazardous Substances Data: 13064-21-6(Hazardous Substances Data)

Usage

General Description

Hepta-1,6-dien-4-ylbenzene is a chemical compound consisting of a heptadiene chain attached to a benzene ring. hepta-1,6-dien-4-ylbenzene is commonly used in the synthesis of various organic compounds and serves as a valuable starting material in organic chemistry research. Hepta-1,6-dien-4-ylbenzene exhibits properties of both alkenes and aromatic compounds due to the presence of the double bonds in the heptadiene chain and the aromaticity of the benzene ring. Its unique structure makes it suitable for a variety of reactions, including Diels-Alder reactions and Friedel-Crafts reactions, making it a versatile building block for the production of a wide range of organic compounds.

Upstream product

• 33558-75-7 allyl(chloromethyl)dimethylsilane 
• 100-52-7 benzaldehyde 
• 762-72-1 allyl-trimethyl-silane 
• 139284-72-3 4-trimethylsiloxy-4-phenyl-1-butene 
• 53847-16-8 3-phenylhex-5-enal 
• 1779-49-3 Methyltriphenylphosphonium bromide 
• 132587-07-6 1-phenylbut-3-enyl acetate 
• 80586-92-1 Allyl cinnamyl ether 
• 4392-24-9 3-bromo-1-phenyl-1-propenyl bromide 
• 581-55-5 benzylidene 1,1-diacetate 
• 24850-33-7 allyltributylstanane 
• 134619-69-5 (1-bromobut-3-en-1-yl)benzene 
• 80735-94-0 1-Phenyl-3-buten-1-ol 

Downstream Products

• 39599-89-8 4-phenylcyclopentene 
• 2448-19-3 C₂₁H₂₃NO 
• 1338500-23-4 C₂₂H₂₀F₃N₃O₂S 
• 1338500-24-5 C₂₁H₁₉F₃N₄O₂S 
• 1338500-25-6 C₁₉H₁₈ClN₃O₂S₂ 
• 7325-50-0 3-phenylpentanedial 

Relevant articles and documents

Preparation of 4-arylcyclopentenes by sequential diallylation of arylaldehydes and ring-closing metathesis

Allylsilane diallylation of aryl aldehydes followed by ring closure metathesis leads to 4-arylcyclopentenes in good yields. Copyright Taylor & Francis, Inc.

FeCl3-Catalyzed Ring-Closing Carbonyl–Olefin Metathesis

Exploiting catalytic carbonyl–olefin metathesis is an ongoing challenge in organic synthesis. Reported herein is an FeCl3-catalyzed ring-closing carbonyl–olefin metathesis. The protocol allows access to a range of carbo-/heterocyclic alkenes wi

Rhodium-catalyzed allylation of benzyl acetates with allylsilanes

Benzyl acetate reacted with allyltrimethylsilane to give an allylation product in the presence of a catalytic amount of the (cyclooctadiene)rhodium(I) chloride dimer {[Rh(cod)Cl]2}, sodium tetrakis[3,5- bis(trifluoromethyl)phenyl]borate (NaBARF), and triphenyl phosphite [P(OPh) 3] in refluxing 1,2-dichloroethane. Primary, secondary and tertiary benzyl acetates could be used for the reaction. Moreover, allylation of gem-benzyl acetate was possible with [Rh(cod)Cl]2, NaBARF, and P(OPh)3. Monoallylation and diallylation of gem-benzyl acetate could be controlled by altering the reaction conditions. Cationic rhodium species generated in situ act as a Lewis acid catalyst to give a benzyl carbocation by elimination of the acetoxy group from the benzylic carbon. Copyright