131309-61-0Relevant articles and documents
Diastereoselectivity in the Addition of Grignard Reagents to Ketones Controlled by the 1,3-Dithiane 1-Oxide Asymmetric Building Block
Page, Philip C. Bulman,Prodger, Jeremy C.,Westwood, Donald
, p. 10355 - 10368 (1993)
2-Acyl-1,3-dithiane 1-oxide undergo diastereoselective addition of Grignard reagents; the degree of selectivity observed is highly dependent upon the solvent and the halide counter-ion used; very high selectivities have been observed under certain reactio
Enantioselective preparation of 2-substituted-1,3-dithiane 1-oxides using modified Sharpless sulphoxidation procedures
Page, Philip C. Bulman,Wilkes, Robin D.,Namwindwa, Ernest S.,Witty, Michael J.
, p. 2125 - 2154 (2007/10/03)
Enantioselective sulphoxidation of a wide range of 2-substituted-1,3-diathianes has been carried out using modified Sharpless conditions to furnish the corresponding sulphoxides in optically enriched form. Deacylation of 2-acyl-1,3-dithiane 1-oxide deriva