132653-29-3Relevant articles and documents
1,5 Allylic abstraction, cyclisation: A new route to five membered carbocycles
Borthwick,Caddick,Parsons
, p. 6911 - 6914 (1990)
A new 1,5 allylic abstraction cyclisation sequence has been developed. The method is based upon a novel radical rearrangement and is applicable to the construction of highly functionalised cyclopentanoid ring systems.
APPROACHES TO BICYCLIC RING SYSTEMS VIA 1,5 ALLYLIC ABSTRACTION CYCLISATION
Borthwick, A. D.,Caddick, S.,Parsons, P. J.
, p. 10655 - 10666 (2007/10/02)
A new 1,5 allylic abstraction, cyclisation sequence has been developed and applied to the synthesis of fused bicyclic systems.Initial studies directed towards the synthesis of the bicyclooctane skeleton are described: vinyl bromide 4 was subjected