91055-81-1

Basic information

• Product Name: α-(2-propenyl)-3-cyclohexen-1-methanol
• Synonyms: α-(2-propenyl)-3-cyclohexen-1-methanol
• CAS NO: 91055-81-1
• Molecular Weight: 152.236
• Mol File: 91055-81-1.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: α-(2-propenyl)-3-cyclohexen-1-methanol(CAS DataBase Reference)
• NIST Chemistry Reference: α-(2-propenyl)-3-cyclohexen-1-methanol(91055-81-1)
• EPA Substance Registry System: α-(2-propenyl)-3-cyclohexen-1-methanol(91055-81-1)

Safety Data

• Hazardous Substances Data: 91055-81-1(Hazardous Substances Data)

Upstream product

• 107-18-6 allyl alcohol 
• 100-50-5 3-Cyclohexene-1-carboxaldehyde 
• 6493-77-2 methyl cyclohex-3-ene-1-carboxylate 
• 762-72-1 allyl-trimethyl-silane 
• 132653-29-3 α-(2-bromopropen-2-yl)-3-cyclohexen-1-methanol 
• 106-95-6 allyl bromide 
• 1730-25-2 allylmagnesium bromide 

Downstream Products

• 103385-60-0 1-cyclohex-3-enyl-but-3-en-1-one 

Relevant articles and documents

Stereoselective Barbier-Type Allylations and Propargylations Mediated by CpTiCl3

CpTiCl2, prepared in situ by manganese reduction of CpTiCl3, is an excellent new system for the Barbier-type allylation and propargylation of carbonyl compounds. It can be used in catalytic amounts when combined with Et3N·HBr/TMSBr, which acts as a regenerating system. The high regio- and stereoselectivity shown by this system makes it useful for prenylation and crotylation processes in the synthesis of natural products.

Oxime-mediated facile access to 5-methylisoxazoles and applications in the synthesis of valdecoxib and oxacillin

A palladium-catalyzed efficient synthesis of 5-methylisoxazoles via oxime-mediated functionalization of unactivated olefins is described. The reaction affords a variety of 5-methylisoxazoles in moderate to good yields. To further demonstrate the utility of the method, the rapid synthesis of valdecoxib and oxacillin is reported. (Chemical Equation Presented).

Pd-catalyzed nucleophilic allylic alkylation of aliphatic aldehydes by the use of allyl alcohols

Under catalysis of Pd(OAc)2-(P-n-Bu)3, Et 2Zn promotes a variety of allyl alcohols to undergo nucleophilic allylation of aliphatic aldehydes and ketones at room temperature and provides homoallyl alcohols in 60-90 and ca. 60% isolated yield, respectively. The reaction is irreversible and kinetically controlled, and unique regio- and stereoselectivities observed for the allylation with unsymmetrically substituted allyl alcohols are discussed.