13271-10-8

Basic information

• Product Name: (E)-1-Chloro-2-propenylbenzene
• Synonyms: (E)-1-Chloro-2-propenylbenzene
• CAS NO: 13271-10-8
• Molecular Formula: C₉H₉Cl
• Molecular Weight: 153
• Product Categories: Aromatics
• Mol File: 13271-10-8.mol
• Article Data: 13

Chemical Properties

• Appearance: /
• CAS DataBase Reference: (E)-1-Chloro-2-propenylbenzene(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-1-Chloro-2-propenylbenzene(13271-10-8)
• EPA Substance Registry System: (E)-1-Chloro-2-propenylbenzene(13271-10-8)

Safety Data

• Hazardous Substances Data: 13271-10-8(Hazardous Substances Data)

Usage

Uses

(E)-1-Chloro-2-propenylbenzene is useful for the preparation of aziridines.

Upstream product

• 89-98-5 2-chloro-benzaldehyde 
• 96-22-0 pentan-3-one 
• 5337-93-9 4'-methylpropiophenone 
• 93-55-0 1-phenyl-propan-1-one 
• 1587-07-1 1-Chloro-2-(2-propenyl)benzene 
• 188014-56-4 2-chlorophenylbutyric acid 

Downstream Products

• 1353948-80-7 (1S,2S)-1-(2-chlorophenyl)propane-1,2-diol 
• 1353948-82-9 (1R,2R)-1-(2-chlorophenyl)propane-1,2-diol 
• 1353949-71-9 (1S,2S)-1-(2-chlorophenyl)-1-hydroxypropan-2-yl carbamate 
• 103360-75-4 1-(2-chlorophenyl)-(S,S)-1,2-propanediol 
• 1385018-77-8 1-(2-chlorophenyl)-(S,S)-1,2-(Bis-trimethylsilanyloxy) propane 
• 1353949-85-5 1-(2-chlorophenyl)-(S)-1-hydroxypropyl-(S)-2-N-methylcarbamate 
• 1353950-35-2 1-(2-chlorophenyl)-(S)-2-hydroxypropyl-(S)-1-carbamate 

Relevant articles and documents

Efficient double bond migration of allylbenzenes catalyzed by Pd(OAc) 2-HFIP system with unique substituent effect

A novel catalyst system of Pd(OAc)2-HFIP induces double-bond migration of allylbenzenes under mild conditions with low catalytic loading to afford 1-propenylbenzenes. The reaction shows a unique substituent effect that is highly dependent on the distance of substituents from the allylic moiety. Thus, the reactivity of substrates bearing a methyl group is ordered in para > meta > ortho, whereas it is entirely reversed as ortho > meta > para for methoxy and chloro substituents.

Method for synthesizing 1, 2-disubstituted olefin through reaction of terminal group olefin and sulfoxide

The invention discloses a method for synthesizing 1, 2-disubstituted olefin by reaction of terminal olefin and sulfoxide. According to the method, terminal olefin with sulfoxide make reaction in one pot in the presence of ferric salt and hydrogen peroxide to generate the 1, 2-disubstituted olefin. sulfoxide is simultaneously used as a hydrocarbylation reagent and a solvent of olefin, and a reaction product is 1, 2-disubstituted olefin of which a terminal carbon atom in terminal olefin is coupled with a sulfoxide alkyl group, so that an olefin carbon chain is increased; the reaction conditionsare mild, the selectivity is high, the yield is high, and industrial production is facilitated.

SULFAMATE DERIVATIVE COMPOUNDS, PROCESSES FOR PREPARING THEM AND THEIR USES

The present invention relates to a pharmaceutical composition for treating or preventing CNS disorders containing a sulfamate derivative compound and/or pharmaceutically acceptable salt thereof as an active ingredient. Furthermore, the present invention relates to a method for treatment or prevention CNS disorders comprising administering a sulfamate derivative compound in a pharmaceutically effective amount to a subject in need of treatment or prevention of CNS disorders.