1587-07-1

Basic information

• Product Name: 1-ALLYL-2-CHLOROBENZENE
• Synonyms: 3-(2-CHLOROPHENYL)-1-PROPENE;1-ALLYL-2-CHLOROBENZENE;3-(2-Chlorophenyl)prop-1-ene;3-(2-Chlorophenyl)prop-1-ene, 1-Chloro-2-(prop-2-en-1-yl)benzene
• CAS NO: 1587-07-1
• Molecular Formula: C₉H₉Cl
• Molecular Weight: 152.62
• Mol File: 1587-07-1.mol
• Article Data: 12

Chemical Properties

• Boiling Point: 195 °C at 760 mmHg
• Flash Point: 71.3 °C
• Appearance: /
• Density: 1.046 g/cm³
• Vapor Pressure: 0.602mmHg at 25°C
• Refractive Index: 1.53
• Storage Temp.: 2-8°C
• Sensitive: Light Sensitive
• CAS DataBase Reference: 1-ALLYL-2-CHLOROBENZENE(CAS DataBase Reference)
• NIST Chemistry Reference: 1-ALLYL-2-CHLOROBENZENE(1587-07-1)
• EPA Substance Registry System: 1-ALLYL-2-CHLOROBENZENE(1587-07-1)

Safety Data

• Hazard Codes: Xi
• Hazardous Substances Data: 1587-07-1(Hazardous Substances Data)

Usage

General Description

1-Allyl-2-Chlorobenzene, also known as Allyl Chlorobenzene, is a low-density, colorless to light yellow liquid chemical compound bearing aromatic and unsaturated aliphatic moieties with a chlorine substitution. It is primarily used in the field of organic synthesis in the pharmaceutical industry. The chemical formula is C9H9Cl and its molecular weight is 154.62 g/mol. It is stable under normal conditions, although it may decompose if heating occurs, producing toxic gases like hydrogen chloride and carbon monoxide. It should be handled with caution due to its flammability and potential to cause skin and eye irritation.

InChI:InChI=1/C9H9Cl/c1-2-5-8-6-3-4-7-9(8)10/h2-4,6-7H,1,5H2

Upstream product

• 694-80-4 2-bromo-1-chlorobenzene 
• 106-95-6 allyl bromide 
• 108-90-7 chlorobenzene 
• 762-72-1 allyl-trimethyl-silane 
• 107-05-1 3-chloroprop-1-ene 
• 591-87-7 Allyl acetate 
• 615-41-8 2-iodochlorobenzene 
• 3900-89-8 2-Chlorobenzeneboronic acid 
• 95-51-2 o-chloroaniline 

Downstream Products

• 143888-46-4 4-Oxo-4-<2-(2-propenyl)phenyl>butanoic acid 
• 77333-71-2 3-methyl-1,2-diphenyl-3-(o-allylphenyl)cyclopropene 
• 89121-25-5 2-methyl-1,3-diphenyl-3-(o-allylphenyl)cyclopropene 
• 13271-06-2 o-diphenylphosphinoallylbenzene 
• 62708-42-3 o-allylbenzaldehyde 
• 114491-39-3 5-Diazo-1-<2-(2-propenyl)phenyl>-2,4-pentanedione 
• 143888-47-5 Methyl 4-oxo-4-<2-(2-propenyl)phenyl>butanoate 
• 62826-19-1 (2-chloro-benzyl)-oxirane 
• 13271-10-8 (E)-1-chloro-2-(prop-1-en-1-yl)benzene 
• 188014-56-4 2-chlorophenylbutyric acid 
• 880653-63-4 3-(2-chlorophenyl)-2-methylpropanoic acid 

Relevant articles and documents

Carbonylative Transformation of Allylarenes with CO Surrogates: Tunable Synthesis of 4-Arylbutanoic Acids, 2-Arylbutanoic Acids, and 4-Arylbutanals

In this Communication, procedures for the selective synthesis of 4-arylbutanoic acids, 2-arylbutanoic acids, and 4-arylbutanals from the same allylbenzenes have been developed. With formic acid or TFBen as the CO surrogate, reactions proceed selectively and effectively under carbon monoxide gas-free conditions.

Cross-Coupling Reactions of Aryldiazonium Salts with Allylsilanes under Merged Gold/Visible-Light Photoredox Catalysis

A method for the cross-coupling reactions of aryldiazonium salts with trialkylallylsilanes via merged gold/photoredox catalysis is described. The reaction is proposed to proceed through a photoredox-promoted generation of an electrophilic arylgold(III) intermediate that undergoes transmetalation with allyltrimethylsilane to form allylarenes.

Phosphazene base-promoted halogen-zinc exchange reaction of aryl iodides using diethylzinc

The use of catalytic t-Bu-P4 base dramatically improved the performance of halogen-zinc exchange of aryl iodides, and the arylzinc derivatives were functionalized under copper-free reaction conditions. The Royal Society of Chemistry 2006.