132910-90-8Relevant articles and documents
Efficient macrocyclization by a novel oxy-oxonia-cope reaction: Synthesis and olfactory properties of new macrocyclic musks
Zou, Yue,Mouhib, Halima,Stahl, Wolfgang,Goeke, Andreas,Wang, Quanrui,Kraft, Philip
supporting information; experimental part, p. 7010 - 7015 (2012/07/03)
Musk made to odor: A new oxy-oxonia-Cope macrocyclization to (3Z)-configured cycloalk-3-en-1-yl formates is reported, which is useful in the synthesis of unsaturated and saturated macrocyclic ketones (see scheme). The synthesized structures provide new insight into the structure-odor correlation of musks, making it likely for macrocyclic and linear alicyclic musks to address the same olfactory receptors.