1333120-11-8

Basic information

• Product Name: tert-butyl (2-bromo-4-chlorophenyl)(2-methylallyl)carbamate
• Synonyms: tert-butyl (2-bromo-4-chlorophenyl)(2-methylallyl)carbamate
• CAS NO: 1333120-11-8
• Molecular Weight: 360.678
• Mol File: 1333120-11-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: tert-butyl (2-bromo-4-chlorophenyl)(2-methylallyl)carbamate(CAS DataBase Reference)
• NIST Chemistry Reference: tert-butyl (2-bromo-4-chlorophenyl)(2-methylallyl)carbamate(1333120-11-8)
• EPA Substance Registry System: tert-butyl (2-bromo-4-chlorophenyl)(2-methylallyl)carbamate(1333120-11-8)

Safety Data

• Hazardous Substances Data: 1333120-11-8(Hazardous Substances Data)

Upstream product

• 384793-16-2 (2-bromo-4-chloro-phenyl)-carbamic acid tert-butyl ester 
• 563-47-3 3-Chloro-2-methylpropene 

Relevant articles and documents

Palladium-catalyzed carbohalogenation: Bromide to iodide exchange and domino processes

Aryl bromides have been used to prepare a variety of nitrogen- and oxygen-containing heterocycles featuring new carbon-carbon and carbon-iodine bonds. This palladium-catalyzed carbohalogenation requires potassium iodide for the reaction to proceed in high yields. Additionally, the first examples of domino carbohalogenation reactions have been demonstrated using both aryl iodide and aryl bromide starting materials. Complex products with multiple rings and stereogenic centers are generated in excellent yields with moderate to excellent diastereoselectivities.