133349-85-6

Basic information

• Product Name: 1-(4''-methoxybenzyl)-1H-benzo[d][1.2.3]triazole
• Synonyms: 1-(4''-methoxybenzyl)-1H-benzo[d][1.2.3]triazole
• CAS NO: 133349-85-6
• Molecular Weight: 239.277
• Mol File: 133349-85-6.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: 1-(4''-methoxybenzyl)-1H-benzo[d][1.2.3]triazole(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(4''-methoxybenzyl)-1H-benzo[d][1.2.3]triazole(133349-85-6)
• EPA Substance Registry System: 1-(4''-methoxybenzyl)-1H-benzo[d][1.2.3]triazole(133349-85-6)

Safety Data

• Hazardous Substances Data: 133349-85-6(Hazardous Substances Data)

Upstream product

• 95-14-7 1,2,3-Benzotriazole 
• 824-94-2 p-methoxybenzyl chloride 
• 104-93-8 p-methylanizole 
• 5720-07-0 4-methoxyphenylboronic acid 
• 2221-02-5 4'-methoxy-3-nitro-[1,1'-biphenyl]-4-amine 
• 5729-16-8 N-(4-methoxy-benzyl)-benzene-1,2-diamine 
• 1262319-47-0 1,1'-((4-methoxyphenyl)methylene)bis(1H-benzo[d][1,2,3]triazole) 
• 105-13-5 4-Methoxybenzyl alcohol 
• 28539-02-8 1-Hydroxymethyl-1H-benzotriazole 
• 100-66-3 methoxybenzene 

Downstream Products

• 133349-93-6 2-(1H-Benzotriazol-1-yl)-2-(4-methoxyphenyl)acetic acid 
• 60702-14-9 1-(p-methoxyphenyl)-1-phenylthiopropane 
• 84570-80-9 2-(4-methoxylphenyl)-4-phenylquinazoline 
• 203070-26-2 1-[(4-Methoxy-phenyl)-bis-phenylselanyl-methyl]-1H-benzotriazole 
• 4231-69-0 1-(4-methoxybenzoyl)-1H-1,2,3-benzotriazole 
• 95-14-7 1,2,3-Benzotriazole 
• 627088-26-0 C₃₁H₂₂ClF₃N₄O₂ 
• 627088-27-1 4-(4-methoxyphenyl)-5-(p-tolyl)-6-[N-(p-tolyl)-N-trifluoroacetyl]amino-2,3-benzo-1,3a,6a-triazapentalene 
• 627088-42-0 4-(4-methoxyphenyl)-6-(p-toluidino)-5-(p-tolyl)-2,3-benzo-1,3a,6a-triazapentalene 

Relevant articles and documents

Synthesis of Structurally Diverse Benzotriazoles via Rapid Diazotization and Intramolecular Cyclization of 1,2-Aryldiamines

An operationally simple method has been developed for the preparation of N-unsubstituted benzotriazoles by diazotization and intramolecular cyclization of a wide range of 1,2-aryldiamines under mild conditions, using a polymer-supported nitrite reagent and p-tosic acid. The functional group tolerance of this approach was further demonstrated with effective activation and cyclization of N-alkyl, -aryl, and -acyl ortho-aminoanilines leading to the synthesis of N1-substituted benzotriazoles. The synthetic utility of this one-pot heterocyclization process was exemplified with the preparation of a number of biologically and medicinally important benzotriazole scaffolds, including an α-amino acid analogue.

Reusable ionic liquid-catalyzed oxidative coupling of azoles and benzylic compounds via sp3 C-N bond formation under metal-free conditions

The heterocyclic ionic liquid-catalyzed direct oxidative amination of benzylic sp3 C-H bonds via intermolecular sp3 C-N bond formation for the synthesis of N-alkylated azoles under metal-free conditions is reported for the first time. The catalyst 1-butylpyridinium iodide can be recycled and reused with similar efficacies for at least eight cycles.

Metal-free, highly efficient organocatalytic amination of benzylic C-H bonds

A new synthetic approach toward direct C-N bond formation through sp 3 C-H activation has been developed under metal-free conditions. Both primary and secondary benzylic C-H substrates could react smoothly with various amines to give only mono-amination products with good to excellent yields. The Royal Society of Chemistry 2013.