133828-01-0Relevant articles and documents
Directive and Shielding Effects of the Trimethylsilyl Group. Unprecedented β-Selectivity in the Reaction of α,β-Epoxyalkylsilanes with Hindered α-Sulphonyl Anions
Jankowski, Pawel,Marczak, Stanislaw,Masnyk, Marek,Wicha, Jerzy
, p. 297 - 298 (2007/10/02)
Anions generated from hindered primary and secondary alkyl phenyl sulphones react with trimethylsilyloxirane to yield a mixture of products of addition in α- and β-positions or exclusively the product of addition in the β-position.