13412-55-0

Basic information

• Product Name: triphenylmethylacetonitrile oxide
• Synonyms: triphenylmethylacetonitrile oxide
• CAS NO: 13412-55-0
• Molecular Weight: 285.345
• Mol File: 13412-55-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: triphenylmethylacetonitrile oxide(CAS DataBase Reference)
• NIST Chemistry Reference: triphenylmethylacetonitrile oxide(13412-55-0)
• EPA Substance Registry System: triphenylmethylacetonitrile oxide(13412-55-0)

Safety Data

• Hazardous Substances Data: 13412-55-0(Hazardous Substances Data)

Upstream product

• 5610-59-3 fulminic acid ; silver-salt 
• 76-83-5 trityl chloride 
• 71-43-2 benzene 

Downstream Products

• 60196-83-0 5-phenyl-3-trityl-4,5-dihydro-isoxazole 
• 41294-27-3 2,2,2,3-tetraphenyl-4-trityl-2,3-dihydro-2λ⁵-[1,3,5,2]oxadiazarsole 
• 123622-72-0 5-butyl-3-(triphenylmethyl)-2-isoxazoline 
• 111379-53-4 5-(3-Butenyl)-3-(triphenylmethyl)-2-isoxazoline 
• 123622-55-9 5-(4-pentenyl)-3-(triphenylmethyl)-2-isoxazoline 
• 123622-57-1 5-(6-heptenyl)-3-(triphenylmethyl)-2-isoxazoline 
• 6639-43-6 2,2,2-triphenylacetonitrile 
• 123622-56-0 5-(5-hexenyl)-3-(triphenylmethyl)-2-isoxazoline 
• 4737-21-7 trityl isocyanate 
• 127347-02-8 3-triphenylmethyl-5-<((2-hydroxyl-2-trimethylsilyoxymethyl)cyclohex-1-yl)methyl>-2-isoxazoline 
• 127347-09-5 3-triphenylmethyl-5-<((2-ethylidene)-cyclohex-1-yl)methyl>-2-isoxazoline 
• 127347-06-2 6-Allyl-3-trityl-1-oxa-2-aza-spiro[4.5]dec-2-ene 
• 127347-03-9 3-triphenylmethyl-5-<((2-methylene)-cyclohex-1-yl)methyl>-2-isoxazoline 
• 127347-11-9 3-triphenylmethyl-5-<((2-ethylene)-cyclopent-1-yl)methyl>-2-isoxazoline 

Relevant articles and documents

A Kinetic Study of the Rearrangement of Triarylacetonitrile Oxides

The thermal rearrangement of triphenylacetonitrile oxide (1a) to triphenylmethyl isocyanate (2) is a first-order process.Rate constants at five temperatures between 116 and 190 deg C were determined giving ΔH(excit.) = 9.3 +/- 1.1 kcal/mol and ΔS(excit.) = -58.2 +/- 2.4 cal/mol*K.The rearrangement of substituted triarylacetonitrile oxides (1b-d) occur only slightly faster than that of 1a.These results are interpreted in terms of a concerted single-step rearrangement in which the highly ordered transition state (6c) has a degree of radical character.