1346523-59-8

Basic information

• Product Name: 4-{[ethyl-(4-methylcoumarin-7-yl)amino]methyl}benzoic acid methyl ester
• Synonyms: 4-{[ethyl-(4-methylcoumarin-7-yl)amino]methyl}benzoic acid methyl ester
• CAS NO: 1346523-59-8
• Molecular Weight: 351.402
• Mol File: 1346523-59-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4-{[ethyl-(4-methylcoumarin-7-yl)amino]methyl}benzoic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 4-{[ethyl-(4-methylcoumarin-7-yl)amino]methyl}benzoic acid methyl ester(1346523-59-8)
• EPA Substance Registry System: 4-{[ethyl-(4-methylcoumarin-7-yl)amino]methyl}benzoic acid methyl ester(1346523-59-8)

Safety Data

• Hazardous Substances Data: 1346523-59-8(Hazardous Substances Data)

Upstream product

• 7159-96-8 ethyl N-(3-hydroxyphenyl)carbamate 
• 591-27-5 m-Hydroxyaniline 
• 101973-09-5 7-[N-(p-toluenesulfonyl)amino]-4-methylcoumarin 
• 58632-48-7 (4-methyl-2-oxo-2H-1-benzopyran-7-yl)carbamic acid ethyl ester 
• 2417-72-3 Methyl 4-(bromomethyl)benzoate 
• 28821-18-3 4-methyl-7-ethylamino-2H-benzopyran-2-one 
• 26093-31-2 7-amino-4-methylcoumarin. 
• 1346523-56-5 7-[ethyl-(4-methanesulfonylphenyl)amino]-4-methylcoumarin 

Downstream Products

• 1346523-61-2 4-{[ethyl-(4-methylcoumarin-7-yl)amino]methyl}benzoic acid 

Relevant articles and documents

Non-conjugated dendrimers with a porphyrin core and coumarin chromophores as peripheral units: Synthesis and photophysical properties

Three porphyrin-cored dendrimers with non-conjugated coumarins as dendrons have been synthesized and characterized. The photophysical properties of the title compounds were investigated by means of UV/Vis absorption and fluorescence spectroscopy in dilute CH2Cl2 solutions and in thin neat films. The intramolecular energy transfer from the coumarin units to the porphyrin core clearly reveals two factors influencing energy-transfer efficiency. Firstly, a better spectral overlap between the absorption spectrum of porphyrin core and the emission spectrum of the coumarin moiety results in high energy-transfer efficiency. Secondly, a long alkyl side-chain improves solubility of dendrimers, but also prevents the coumarins from self-quenching. Hence, the dendrimer with N-octyl groups possesses a higher efficiency than that with N-ethyl groups. The dendrimers emit red light with higher fluorescence quantum yields over the free porphyrin.