135094-36-9

Basic information

• Product Name: Bicyclo[2.2.1]heptane-2,5-diol, (1R,2S,4R,5S)-
• CAS NO: 135094-36-9
• Molecular Formula: C7H12O2
• Molecular Weight: 128.171
• Mol File: 135094-36-9.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: Bicyclo[2.2.1]heptane-2,5-diol, (1R,2S,4R,5S)-(CAS DataBase Reference)
• NIST Chemistry Reference: Bicyclo[2.2.1]heptane-2,5-diol, (1R,2S,4R,5S)-(135094-36-9)
• EPA Substance Registry System: Bicyclo[2.2.1]heptane-2,5-diol, (1R,2S,4R,5S)-(135094-36-9)

Safety Data

• Hazardous Substances Data: 135094-36-9(Hazardous Substances Data)

Upstream product

• 121-46-0 bicyclo[2.2.1]hepta-2,5-diene 
• 27943-47-1 norbornane-2,5-dione 
• 121-46-0 bicyclo[2.2.1]hepta-2,5-diene 
• 694-97-3 endo-5-norbornen-2-ol 
• 2888-90-6 5-norbornene-2-carbonitrile 
• 2890-96-2 5-norbornene-2-carbonitrile 
• 78987-90-3 (1RS,2RS,4SR,5SR,6RS)-3-oxatricyclo<3.2.1.0^2,4>octan-6-yl acetate 
• 5257-38-5 (+/-)-exo-5-acetoxybicyclo<2.2.1>heptan-2-one 
• 5763-72-4 (+/-)-2endo,6endo-epoxido-norbornane-3exo-ol 
• 7329-28-4 (1RS,2RS,4SR,5SR,6RS)-3-oxatricyclo<3.2.1.0^2,4>octan-6-ol 

Downstream Products

• 27943-47-1 norbornane-2,5-dione 
• 1384282-27-2 (1S,2S,4S,5S)-N₂,N₅-dibenzyl-N₂,N₅-dimethylbicyclo[2.2.1]heptane-2,5-diamine 
• 698353-48-9 C₂₁H₂₆N₂ 
• 1334758-60-9 ((1R,2S,4R,5S)-5-(benzyloxy)bicyclo[2.2.1]heptan-2-yloxy)(tert-butyl)diphenylsilane 
• 870708-23-9 (1R,2S,4R,5S)-5-(benzyloxy)bicyclo[2.2.1]heptan-2-ol 
• 1334758-84-7 2-((1R,2S,4R,5S)-5-(tert-butyldiphenylsilyloxy)bicyclo[2.2.1]heptan-2-ylamino)-5-isopropyl-5-methylthiazol-4(5H)-one 
• 1191465-50-5 2-((1R,2S,4R,5S)-5-(tert-butyldiphenylsilyloxy)bicyclo[2.2.1]heptan-2-yl)isoindoline-1,3-dione 
• 1334758-81-4 (1R,4R,5S)-5-(tert-butyldiphenylsilyloxy)bicyclo[2.2.1]heptan-2-one 
• 1334758-82-5 2-((1R,2S,4R,5S)-5-(tert-butyldiphenylsilyloxy)bicyclo[2.2.1]heptan-2-ylamino)-5-isopropylthiazol-4(5H)-one 
• 1191465-55-0 1-((1R,2S,4R,5S)-5-(tert-butyldiphenylsilyloxy)bicyclo[2.2.1]heptan-2-yl)thiourea 
• 1191464-92-2 (1R,2R,4R,5S)-5-(tert-butyldiphenylsilyloxy)bicyclo[2.2.1]heptan-2-ol 
• 1334758-61-0 (1R,2S,4R,5S)-5-(tert-butyldiphenylsilyloxy)bicyclo[2.2.1]heptan-2-ol 
• 608489-09-4 (1R,4R)-spiro[5-trifluoromethanesulfonyloxybicyclo[2.2.1]hept-5-ene-2,2'-[1,3]dioxolane] 
• 539834-16-7 2,2'-[(1R,2R,4R,5R)-bicyclo[2.2.1]heptane-2,5-diylbis(nitrilomethylidyne)]bis(4,6-di-tert-butylphenol) 

Relevant articles and documents

Evaluation of the chiral DIANANE backbone as ligand for organolithium reagents

Novel endo,endo-2,5-diaminonorbonane-derived tertiary C2- symmetrical diamines were synthesized via the one-pot reductive amination of enantiomerically pure norbornane-2,5-dione. These ligands were applied to various catalytic reactions such as asymmetric deprotonation, asymmetric bromine-lithium exchange, and enantioselective addition of aryl- and allkylithium reagents to aromatic aldimines. Copyright

Enantioselective Synthesis of DIANANE, a Novel C2-Symmetric Chiral Diamine for Asymmetric Catalysis

DIANANE (endo,endo-2,5-diaminonorbornane) is a novel chiral C 2-symmetric diamine, based on the rigid bicyclo[2.2.1]heptane scaffold. Schiff-base ligands derived from DIANANE have already found use in asymmetric catalysis, e.g., in the highly e

Syntheses in the isocamphane series XLII [1]. Synthesis and odour of 5-exo-hydroxycamphene (isonojigiku alcohol)

The synthesis of the title compound is described. Hydroxylation of the endocyclic double bond of 2-acetyl-3,3-dimethylnorborn-5-ene furnished a mixture of nojigiku alcohol and the title compound. A shorter route leads from 2,5-norbornadiene solely to the desired camphoraceous smelling new hydroxy derivative to which the name isonojigiku alcohol is assigned.