1352449-01-4

Basic information

• Product Name: N-methyl-N-(2-chlorophenyl)-2'-aminoacetophenone
• Synonyms: N-methyl-N-(2-chlorophenyl)-2'-aminoacetophenone
• CAS NO: 1352449-01-4
• Molecular Weight: 259.735
• Mol File: 1352449-01-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-methyl-N-(2-chlorophenyl)-2'-aminoacetophenone(CAS DataBase Reference)
• NIST Chemistry Reference: N-methyl-N-(2-chlorophenyl)-2'-aminoacetophenone(1352449-01-4)
• EPA Substance Registry System: N-methyl-N-(2-chlorophenyl)-2'-aminoacetophenone(1352449-01-4)

Safety Data

• Hazardous Substances Data: 1352449-01-4(Hazardous Substances Data)

Upstream product

• 95-51-2 o-chloroaniline 
• 1352449-00-3 2-chloro-N-(2-(2-methyl-1,3-dioxolan-2-yl)phenyl)aniline 
• 50777-64-5 2-(2-bromophenyl)-2-methyl-1,3-dioxolane 

Downstream Products

• 4904-83-0 5-methyl-10-oxo-10,11-dihydro-5H-dibenzo[b,f]azepine 

Relevant articles and documents

Synthesis of benzo-fused heterocycles by intramolecular α-arylation of ketone enolate anions

A two-step synthesis of six-, seven-, eight-, and nine-member benzo-fused heterocycles in good to excellent yields is reported. The synthetic strategy involves the generation of a new intramolecular α-aryl ketone bond by the photostimulated SRN1 reaction of ketone enolate anions linked to a pendant haloarene as the key step. On the other hand, an intramolecular C Ar-CAr coupling led to the formation of five- and six-member benzo-fused heterocycles (9H-carbazole and phenanthridine) when an aromatic amide anion is competitively formed.