1355016-92-0

Basic information

• Product Name: C₂₇H₃₇NO₃Si
• CAS NO: 1355016-92-0
• Molecular Weight: 451.681
• Mol File: 1355016-92-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₂₇H₃₇NO₃Si(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₇H₃₇NO₃Si(1355016-92-0)
• EPA Substance Registry System: C₂₇H₃₇NO₃Si(1355016-92-0)

Safety Data

• Hazardous Substances Data: 1355016-92-0(Hazardous Substances Data)

Upstream product

• 87727-28-4 (S)-2-tert-butyl-dimethyl-silanyloxy propanal 
• 74181-34-3 2,2,-dimethyl-1,3-dioxan-5-one 
• 209627-36-1 (2S)-2-(((tert-butyldiphenylsilyl)oxy)methyl)idinepyrrol 
• 1355017-06-9 C₂₉H₃₅NOSi 
• 1355017-01-4 C₂₈H₃₉NOSi 
• 1355016-97-5 C₃₁H₃₇NOSi 
• 1355016-96-4 C₃₀H₃₅NOSi 
• 1355016-90-8 C₃₁H₃₇NO₃Si 
• 1355016-95-3 C₂₇H₃₇NOSi 

Downstream Products

• 1355016-90-8 C₃₁H₃₇NO₃Si 
• 74181-34-3 2,2,-dimethyl-1,3-dioxan-5-one 
• 209627-36-1 (2S)-2-(((tert-butyldiphenylsilyl)oxy)methyl)idinepyrrol 

Relevant articles and documents

Relative tendency of carbonyl compounds to form enamines

Equilibria between carbonyl compounds and their enamines (from O-TBDPS-derived prolinol) have been examined by NMR spectroscopy in DMSO-d 6. By comparing the exchange reactions between pairs (enamine A + carbonyl B → carbonyl A + enamine B), a quite general scale of the tendency of carbonyl groups to form enamines has been established. Aldehydes quickly give enamines that are relatively more stable than those of ketones, but there are exceptions to this expected rule; for example, 1,3-dihydroxyacetone acetals or 3,5-dioxacyclohexanones (2-phenyl-1,3-dioxan-5-one and 2,2-dimethyl-1,3- dioxan-5-one) show a greater tendency to afford enamines than many α-substituted aldehydes.